Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes

Chaoyuan Zeng; Guoli Shen; Fan Yang; Jingchao Chen; Xuexin Zhang; Cuiping Gu; Yongyun Zhou; Baomin Fan

doi:10.1021/acs.orglett.8b02980

Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes

Chaoyuan Zeng, Guoli Shen, Fan Yang, Jingchao Chen^*, Xuexin Zhang, Cuiping Gu, Yongyun Zhou, Baomin Fan

^*Corresponding author for this work

Yunnan Minzu University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.

Original language	English
Pages (from-to)	6859-6862
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	21
DOIs	https://doi.org/10.1021/acs.orglett.8b02980
Publication status	Published - 2 Nov 2018
Externally published	Yes

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10.1021/acs.orglett.8b02980

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title = "Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes",

abstract = "The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.",

author = "Chaoyuan Zeng and Guoli Shen and Fan Yang and Jingchao Chen and Xuexin Zhang and Cuiping Gu and Yongyun Zhou and Baomin Fan",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

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doi = "10.1021/acs.orglett.8b02980",

language = "English",

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journal = "Organic Letters",

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TY - JOUR

T1 - Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide

T2 - An Effective Method for the Preparation of Iodoalkanes

AU - Zeng, Chaoyuan

AU - Shen, Guoli

AU - Yang, Fan

AU - Chen, Jingchao

AU - Zhang, Xuexin

AU - Gu, Cuiping

AU - Zhou, Yongyun

AU - Fan, Baomin

PY - 2018/11/2

Y1 - 2018/11/2

N2 - The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.

AB - The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.

UR - http://www.scopus.com/inward/record.url?scp=85055158780&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.8b02980

DO - 10.1021/acs.orglett.8b02980

M3 - Article

C2 - 30350672

AN - SCOPUS:85055158780

SN - 1523-7060

VL - 20

SP - 6859

EP - 6862

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes

Abstract

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