Regulating photochromism of viologen-bearing coordination polymers via the variation of electron-donating/withdrawing groups on organic ligands

Ming Chen; Li Sun; Xiao Dong Yang; Rui Yun Guo; Qi Qi Zhang; Jie Zhang

doi:10.1016/j.inoche.2017.12.006

Regulating photochromism of viologen-bearing coordination polymers via the variation of electron-donating/withdrawing groups on organic ligands

Ming Chen, Li Sun, Xiao Dong Yang, Rui Yun Guo, Qi Qi Zhang, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The substituent effect prevalent in organic compounds has been applied to adjusting the photochromism of viologen-bearing coordination polymers, which enable the isoreticular compounds, {[Cd(Bpybc)_0.5(mip)(H₂O)]·2H₂O}_n (Cd-mip) and {[Cd(Bpybc)_0.5(nip)(H₂O)]·H₂O}_n (Cd-nip), to display different photoresponse behaviors owing to the contribution from the electron-donating/withdrawing group on the auxiliary ligand. The present work demonstrates a practical way to regulate photochromism of target coordination polymer.

Original language	English
Pages (from-to)	53-56
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	87
DOIs	https://doi.org/10.1016/j.inoche.2017.12.006
Publication status	Published - Jan 2018

Keywords

Coordination polymers
Photochromism
Substituent effect
Viologen

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10.1016/j.inoche.2017.12.006

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title = "Regulating photochromism of viologen-bearing coordination polymers via the variation of electron-donating/withdrawing groups on organic ligands",

abstract = "The substituent effect prevalent in organic compounds has been applied to adjusting the photochromism of viologen-bearing coordination polymers, which enable the isoreticular compounds, {[Cd(Bpybc)0.5(mip)(H2O)]·2H2O}n (Cd-mip) and {[Cd(Bpybc)0.5(nip)(H2O)]·H2O}n (Cd-nip), to display different photoresponse behaviors owing to the contribution from the electron-donating/withdrawing group on the auxiliary ligand. The present work demonstrates a practical way to regulate photochromism of target coordination polymer.",

keywords = "Coordination polymers, Photochromism, Substituent effect, Viologen",

author = "Ming Chen and Li Sun and Yang, {Xiao Dong} and Guo, {Rui Yun} and Zhang, {Qi Qi} and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2018",

month = jan,

doi = "10.1016/j.inoche.2017.12.006",

language = "English",

volume = "87",

pages = "53--56",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - Regulating photochromism of viologen-bearing coordination polymers via the variation of electron-donating/withdrawing groups on organic ligands

AU - Chen, Ming

AU - Sun, Li

AU - Yang, Xiao Dong

AU - Guo, Rui Yun

AU - Zhang, Qi Qi

AU - Zhang, Jie

PY - 2018/1

Y1 - 2018/1

N2 - The substituent effect prevalent in organic compounds has been applied to adjusting the photochromism of viologen-bearing coordination polymers, which enable the isoreticular compounds, {[Cd(Bpybc)0.5(mip)(H2O)]·2H2O}n (Cd-mip) and {[Cd(Bpybc)0.5(nip)(H2O)]·H2O}n (Cd-nip), to display different photoresponse behaviors owing to the contribution from the electron-donating/withdrawing group on the auxiliary ligand. The present work demonstrates a practical way to regulate photochromism of target coordination polymer.

AB - The substituent effect prevalent in organic compounds has been applied to adjusting the photochromism of viologen-bearing coordination polymers, which enable the isoreticular compounds, {[Cd(Bpybc)0.5(mip)(H2O)]·2H2O}n (Cd-mip) and {[Cd(Bpybc)0.5(nip)(H2O)]·H2O}n (Cd-nip), to display different photoresponse behaviors owing to the contribution from the electron-donating/withdrawing group on the auxiliary ligand. The present work demonstrates a practical way to regulate photochromism of target coordination polymer.

KW - Coordination polymers

KW - Photochromism

KW - Substituent effect

KW - Viologen

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U2 - 10.1016/j.inoche.2017.12.006

DO - 10.1016/j.inoche.2017.12.006

M3 - Article

AN - SCOPUS:85037708108

SN - 1387-7003

VL - 87

SP - 53

EP - 56

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Regulating photochromism of viologen-bearing coordination polymers via the variation of electron-donating/withdrawing groups on organic ligands

Abstract

Keywords

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