Reduction of carbodiimides by a dialumane through insertion and cycloaddition

Lin Xiao; Weixing Chen; Lingyi Shen; Li Liu; Yujie Xue; Yanxia Zhao; Xiao Juan Yang

doi:10.1039/d0cc02048f

Reduction of carbodiimides by a dialumane through insertion and cycloaddition

Lin Xiao, Weixing Chen, Lingyi Shen, Li Liu, Yujie Xue, Yanxia Zhao^*, Xiao Juan Yang

^*Corresponding author for this work

Northwest University China

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The dialumane [L²⁻Al^II-Al^IIL²⁻] (L = [(2,6-iPr₂C₆H₃)NC(Me)]₂; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr₂C₆H₃,tBu), the reactions are sterically controlled and lead to the formamidinate products.

Original language	English
Pages (from-to)	6352-6355
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	47
DOIs	https://doi.org/10.1039/d0cc02048f
Publication status	Published - 14 Jun 2020
Externally published	Yes

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title = "Reduction of carbodiimides by a dialumane through insertion and cycloaddition",

abstract = "The dialumane [L2−AlII-AlIIL2−] (L = [(2,6-iPr2C6H3)NC(Me)]2; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr2C6H3,tBu), the reactions are sterically controlled and lead to the formamidinate products.",

author = "Lin Xiao and Weixing Chen and Lingyi Shen and Li Liu and Yujie Xue and Yanxia Zhao and Yang, {Xiao Juan}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

month = jun,

day = "14",

doi = "10.1039/d0cc02048f",

language = "English",

volume = "56",

pages = "6352--6355",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Reduction of carbodiimides by a dialumane through insertion and cycloaddition

AU - Xiao, Lin

AU - Chen, Weixing

AU - Shen, Lingyi

AU - Liu, Li

AU - Xue, Yujie

AU - Zhao, Yanxia

AU - Yang, Xiao Juan

PY - 2020/6/14

Y1 - 2020/6/14

N2 - The dialumane [L2−AlII-AlIIL2−] (L = [(2,6-iPr2C6H3)NC(Me)]2; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr2C6H3,tBu), the reactions are sterically controlled and lead to the formamidinate products.

AB - The dialumane [L2−AlII-AlIIL2−] (L = [(2,6-iPr2C6H3)NC(Me)]2; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr2C6H3,tBu), the reactions are sterically controlled and lead to the formamidinate products.

UR - http://www.scopus.com/inward/record.url?scp=85086332034&partnerID=8YFLogxK

U2 - 10.1039/d0cc02048f

DO - 10.1039/d0cc02048f

M3 - Article

C2 - 32390025

AN - SCOPUS:85086332034

SN - 1359-7345

VL - 56

SP - 6352

EP - 6355

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Reduction of carbodiimides by a dialumane through insertion and cycloaddition

Abstract

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