Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions

Chuancheng Jia; Iain M. Grace; Peiqi Wang; Abdelkareem Almeshal; Zhihong Huang; Yiliu Wang; Peng Chen; Laiyuan Wang; Jingyuan Zhou; Ziying Feng; Zipeng Zhao; Yu Huang; Colin J. Lambert; Xiangfeng Duan

doi:10.1016/j.chempr.2020.02.018

Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions

Chuancheng Jia, Iain M. Grace, Peiqi Wang, Abdelkareem Almeshal, Zhihong Huang, Yiliu Wang, Peng Chen, Laiyuan Wang, Jingyuan Zhou, Ziying Feng, Zipeng Zhao, Yu Huang, Colin J. Lambert^*, Xiangfeng Duan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Controlling charge transport through molecular-scale devices is of crucial importance. This article reports an effective route to tailor cross-plane charge transport in a vertical molecular tunneling junction through controlled chemical or electrochemical redox reaction in the self-assembled molecular monolayers buried under graphene. This redox control of the cross-plane charge transport is important for exploring fundamental mechanisms and realizing new functionalities in molecular electronics.

Original language	English
Pages (from-to)	1172-1182
Number of pages	11
Journal	Chem
Volume	6
Issue number	5
DOIs	https://doi.org/10.1016/j.chempr.2020.02.018
Publication status	Published - 14 May 2020
Externally published	Yes

Keywords

SDG9: Industry, innovation, and infrastructure
charge transport
confined redox reaction
ferrocene
graphene
interfacial coupling
molecular junctions
reversible switch
self-assembled monolayer

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10.1016/j.chempr.2020.02.018

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title = "Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions",

abstract = "Controlling charge transport through molecular-scale devices is of crucial importance. This article reports an effective route to tailor cross-plane charge transport in a vertical molecular tunneling junction through controlled chemical or electrochemical redox reaction in the self-assembled molecular monolayers buried under graphene. This redox control of the cross-plane charge transport is important for exploring fundamental mechanisms and realizing new functionalities in molecular electronics.",

keywords = "SDG9: Industry, innovation, and infrastructure, charge transport, confined redox reaction, ferrocene, graphene, interfacial coupling, molecular junctions, reversible switch, self-assembled monolayer",

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doi = "10.1016/j.chempr.2020.02.018",

language = "English",

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T1 - Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions

AU - Jia, Chuancheng

AU - Grace, Iain M.

AU - Wang, Peiqi

AU - Almeshal, Abdelkareem

AU - Huang, Zhihong

AU - Wang, Yiliu

AU - Chen, Peng

AU - Wang, Laiyuan

AU - Zhou, Jingyuan

AU - Feng, Ziying

AU - Zhao, Zipeng

AU - Huang, Yu

AU - Lambert, Colin J.

AU - Duan, Xiangfeng

PY - 2020/5/14

Y1 - 2020/5/14

N2 - Controlling charge transport through molecular-scale devices is of crucial importance. This article reports an effective route to tailor cross-plane charge transport in a vertical molecular tunneling junction through controlled chemical or electrochemical redox reaction in the self-assembled molecular monolayers buried under graphene. This redox control of the cross-plane charge transport is important for exploring fundamental mechanisms and realizing new functionalities in molecular electronics.

AB - Controlling charge transport through molecular-scale devices is of crucial importance. This article reports an effective route to tailor cross-plane charge transport in a vertical molecular tunneling junction through controlled chemical or electrochemical redox reaction in the self-assembled molecular monolayers buried under graphene. This redox control of the cross-plane charge transport is important for exploring fundamental mechanisms and realizing new functionalities in molecular electronics.

KW - SDG9: Industry, innovation, and infrastructure

KW - charge transport

KW - confined redox reaction

KW - ferrocene

KW - graphene

KW - interfacial coupling

KW - molecular junctions

KW - reversible switch

KW - self-assembled monolayer

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DO - 10.1016/j.chempr.2020.02.018

M3 - Article

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SN - 2451-9308

VL - 6

SP - 1172

EP - 1182

JO - Chem

JF - Chem

IS - 5

ER -

Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions

Abstract

Keywords

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