TY - JOUR
T1 - Recent progress of Mn-based NASICON-type sodium ion cathodes
AU - Liu, Yang
AU - Sun, Chen
AU - Li, Yang
AU - Jin, Haibo
AU - Zhao, Yongjie
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/3
Y1 - 2023/3
N2 - Sodium-ion batteries have attracted extensive concern and research for smart grids and large-scale energy storage systems owing to the low cost and high natural abundance of Na resource. Selecting appropriate electrode materials is beneficial to the development and research of SIBs. Compared with typical NASICON-structure Na3V2(PO4)3, Mn-based NASICON-type cathodes for sodium-ion batteries reveal highly attractive application prospects due to their high earth-abundance and rich valence states of elemental Mn. Besides, the adjustable merit of NASICON structure endows a big family of Mn-based material system with enriched compositions. In this review, Mn-based NASICON-type sodium ion cathodes are briefed to provide a comprehensive overview of their recent advance. The structure, electrochemical reaction mechanism and properties are demonstrated. Moreover, the critical issues happened to lots of Mn-based materials, such as Mn dissolution, Jahn–Teller distortion, the influence of liquid electrolyte, etc., are discussed. At last, perspectives and challenges about the future development of Mn-based NASICON-type cathodes are presented as well. We believe that this review can serve as a reference for preparing Mn-based NASICONs toward the utilization of both nonaqueous and aqueous rechargeable devices beyond sodium ion batteries.
AB - Sodium-ion batteries have attracted extensive concern and research for smart grids and large-scale energy storage systems owing to the low cost and high natural abundance of Na resource. Selecting appropriate electrode materials is beneficial to the development and research of SIBs. Compared with typical NASICON-structure Na3V2(PO4)3, Mn-based NASICON-type cathodes for sodium-ion batteries reveal highly attractive application prospects due to their high earth-abundance and rich valence states of elemental Mn. Besides, the adjustable merit of NASICON structure endows a big family of Mn-based material system with enriched compositions. In this review, Mn-based NASICON-type sodium ion cathodes are briefed to provide a comprehensive overview of their recent advance. The structure, electrochemical reaction mechanism and properties are demonstrated. Moreover, the critical issues happened to lots of Mn-based materials, such as Mn dissolution, Jahn–Teller distortion, the influence of liquid electrolyte, etc., are discussed. At last, perspectives and challenges about the future development of Mn-based NASICON-type cathodes are presented as well. We believe that this review can serve as a reference for preparing Mn-based NASICONs toward the utilization of both nonaqueous and aqueous rechargeable devices beyond sodium ion batteries.
KW - Jahn–Teller distortion
KW - Microstructure
KW - Mn-based NASICONs
KW - Scalable energy storage
KW - Sodium ion cathode
UR - http://www.scopus.com/inward/record.url?scp=85147794434&partnerID=8YFLogxK
U2 - 10.1016/j.ensm.2023.02.005
DO - 10.1016/j.ensm.2023.02.005
M3 - Review article
AN - SCOPUS:85147794434
SN - 2405-8297
VL - 57
SP - 69
EP - 80
JO - Energy Storage Materials
JF - Energy Storage Materials
ER -
