Recent Advances in Organic Room Temperature Phosphorescence of Triphenylamine-Based Doping Systems

Gengchen Li, Wenbo Dai, Yunxiang Lei, Jianbing Shi, Bin Tong, Zhengxu Cai*, Yuping Dong*

*Corresponding author for this work

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Abstract

The host–guest doping strategy has become one of the most effective approaches to realize pure organic room temperature phosphorescence (RTP). Crystalline small molecules can provide a rigid environment that restricts the molecular motion of luminescent guests, thus enhancing phosphorescence emission. Triphenylamine (TPA) is a classic crystalline small molecule matrix that, when doped with designed guest molecules, enables tunable RTP properties and diverse functionalities. These properties afford TPA-based doping systems with numerous applications in anticounterfeiting, bio-imaging, and multiple responsive sensing. In this concept, design strategies, luminescence mechanisms, and applications of TPA-based host-guest doping systems are summarized. Moreover, the future prospects of TPA-based RTP materials are proposed.

Original languageEnglish
Article numbere202200198
JournalChemPhotoChem
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 2023

Keywords

  • bioimaging
  • energy transfer
  • host-guest systems
  • room temperature phosphorescence
  • triphenylamine

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Li, G., Dai, W., Lei, Y., Shi, J., Tong, B., Cai, Z., & Dong, Y. (2023). Recent Advances in Organic Room Temperature Phosphorescence of Triphenylamine-Based Doping Systems. ChemPhotoChem, 7(3), Article e202200198. https://doi.org/10.1002/cptc.202200198