Chen, W., Pei, J., He, C. T., Wan, J., Ren, H., Zhu, Y., Wang, Y., Dong, J., Tian, S., Cheong, W. C., Lu, S., Zheng, L., Zheng, X., Yan, W., Zhuang, Z., Chen, C., Peng, Q., Wang, D., & Li, Y. (2017). Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction. Angewandte Chemie - International Edition, 56(50), 16086-16090. https://doi.org/10.1002/anie.201710599
Chen, Wenxing ; Pei, Jiajing ; He, Chun Ting et al. / Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction. In: Angewandte Chemie - International Edition. 2017 ; Vol. 56, No. 50. pp. 16086-16090.
@article{738854bd4fc34de0b1f784aab0736cb1,
title = "Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction",
abstract = "The highly efficient electrochemical hydrogen evolution reaction (HER) provides a promising pathway to resolve energy and environment problems. An electrocatalyst was designed with single Mo atoms (Mo-SAs) supported on N-doped carbon having outstanding HER performance. The structure of the catalyst was probed by aberration-corrected scanning transmission electron microscopy (AC-STEM) and X-ray absorption fine structure (XAFS) spectroscopy, indicating the formation of Mo-SAs anchored with one nitrogen atom and two carbon atoms (Mo1N1C2). Importantly, the Mo1N1C2 catalyst displayed much more excellent activity compared with Mo2C and MoN, and better stability than commercial Pt/C. Density functional theory (DFT) calculation revealed that the unique structure of Mo1N1C2 moiety played a crucial effect to improve the HER performance. This work opens up new opportunities for the preparation and application of highly active and stable Mo-based HER catalysts.",
keywords = "N-doped carbon, electrocatalysis, hydrogen evolution reaction, molybdenum, single atoms",
author = "Wenxing Chen and Jiajing Pei and He, {Chun Ting} and Jiawei Wan and Hanlin Ren and Youqi Zhu and Yu Wang and Juncai Dong and Shubo Tian and Cheong, {Weng Chon} and Siqi Lu and Lirong Zheng and Xusheng Zheng and Wensheng Yan and Zhongbin Zhuang and Chen Chen and Qing Peng and Dingsheng Wang and Yadong Li",
note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = dec,
day = "11",
doi = "10.1002/anie.201710599",
language = "English",
volume = "56",
pages = "16086--16090",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "50",
}
Chen, W, Pei, J, He, CT, Wan, J, Ren, H, Zhu, Y, Wang, Y, Dong, J, Tian, S, Cheong, WC, Lu, S, Zheng, L, Zheng, X, Yan, W, Zhuang, Z, Chen, C, Peng, Q, Wang, D & Li, Y 2017, 'Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction', Angewandte Chemie - International Edition, vol. 56, no. 50, pp. 16086-16090. https://doi.org/10.1002/anie.201710599
Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction. /
Chen, Wenxing; Pei, Jiajing; He, Chun Ting et al.
In:
Angewandte Chemie - International Edition, Vol. 56, No. 50, 11.12.2017, p. 16086-16090.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction
AU - Chen, Wenxing
AU - Pei, Jiajing
AU - He, Chun Ting
AU - Wan, Jiawei
AU - Ren, Hanlin
AU - Zhu, Youqi
AU - Wang, Yu
AU - Dong, Juncai
AU - Tian, Shubo
AU - Cheong, Weng Chon
AU - Lu, Siqi
AU - Zheng, Lirong
AU - Zheng, Xusheng
AU - Yan, Wensheng
AU - Zhuang, Zhongbin
AU - Chen, Chen
AU - Peng, Qing
AU - Wang, Dingsheng
AU - Li, Yadong
N1 - Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/12/11
Y1 - 2017/12/11
N2 - The highly efficient electrochemical hydrogen evolution reaction (HER) provides a promising pathway to resolve energy and environment problems. An electrocatalyst was designed with single Mo atoms (Mo-SAs) supported on N-doped carbon having outstanding HER performance. The structure of the catalyst was probed by aberration-corrected scanning transmission electron microscopy (AC-STEM) and X-ray absorption fine structure (XAFS) spectroscopy, indicating the formation of Mo-SAs anchored with one nitrogen atom and two carbon atoms (Mo1N1C2). Importantly, the Mo1N1C2 catalyst displayed much more excellent activity compared with Mo2C and MoN, and better stability than commercial Pt/C. Density functional theory (DFT) calculation revealed that the unique structure of Mo1N1C2 moiety played a crucial effect to improve the HER performance. This work opens up new opportunities for the preparation and application of highly active and stable Mo-based HER catalysts.
AB - The highly efficient electrochemical hydrogen evolution reaction (HER) provides a promising pathway to resolve energy and environment problems. An electrocatalyst was designed with single Mo atoms (Mo-SAs) supported on N-doped carbon having outstanding HER performance. The structure of the catalyst was probed by aberration-corrected scanning transmission electron microscopy (AC-STEM) and X-ray absorption fine structure (XAFS) spectroscopy, indicating the formation of Mo-SAs anchored with one nitrogen atom and two carbon atoms (Mo1N1C2). Importantly, the Mo1N1C2 catalyst displayed much more excellent activity compared with Mo2C and MoN, and better stability than commercial Pt/C. Density functional theory (DFT) calculation revealed that the unique structure of Mo1N1C2 moiety played a crucial effect to improve the HER performance. This work opens up new opportunities for the preparation and application of highly active and stable Mo-based HER catalysts.
KW - N-doped carbon
KW - electrocatalysis
KW - hydrogen evolution reaction
KW - molybdenum
KW - single atoms
UR - http://www.scopus.com/inward/record.url?scp=85037332079&partnerID=8YFLogxK
U2 - 10.1002/anie.201710599
DO - 10.1002/anie.201710599
M3 - Article
C2 - 29076292
AN - SCOPUS:85037332079
SN - 1433-7851
VL - 56
SP - 16086
EP - 16090
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 50
ER -
Chen W, Pei J, He CT, Wan J, Ren H, Zhu Y et al. Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction. Angewandte Chemie - International Edition. 2017 Dec 11;56(50):16086-16090. doi: 10.1002/anie.201710599
