Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu; Mu Hua Huang

doi:10.1021/ol0609210

Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu^*, Mu Hua Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both ¹H and ¹³C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

Original language	English
Pages (from-to)	3021-3024
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	14
DOIs	https://doi.org/10.1021/ol0609210
Publication status	Published - 6 Jul 2006
Externally published	Yes

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10.1021/ol0609210

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abstract = "Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.",

author = "Yu, {Chu Yi} and Huang, {Mu Hua}",

year = "2006",

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AB - Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

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Radicamines A and B: Synthesis and revision of the absolute configuration

Abstract

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