Preparation of Fe2O3/CNTs and its catalytic mechanism on thermal decomposition of RDX

Qing Zhong Cui*, Qing Jie Jiao, Wei Dong Zhao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Nano-Fe2O3/CNTs catalyzers were synthesized by the sol-gel methods. The technology parameters were optimized by an orthogonal test. The appearance of products was characterized by SEM, TEM and XRD. The catalytic properties of Fe2O3/CNTs on thermal decomposition of RDX were determined by using DSC method. The results show that the surface of CNTs is coated with Fe2O3. When mass fraction of Fe 2O3/CNTs is about 5%, Fe2O3/CNTs catalyzers make the peak temperature of DSC curve for thermal decomposition of RDX decrease by 14. 1°C, and the activation energy of thermal decomposition reaction of RDX obtained by Kissinger method decrease by 38. 5%.

Original languageEnglish
Pages (from-to)68-71
Number of pages4
JournalHuozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume32
Issue number4
Publication statusPublished - 2009

Keywords

  • Activation energy
  • CNTs
  • Catalyzer
  • Physical chemistry
  • RDX
  • Thermal decomposition

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Cui, Q. Z., Jiao, Q. J., & Zhao, W. D. (2009). Preparation of Fe2O3/CNTs and its catalytic mechanism on thermal decomposition of RDX. Huozhayao Xuebao/Chinese Journal of Explosives and Propellants, 32(4), 68-71.