Porous bimetallic Mn2Co1Ox catalysts prepared by a one-step combustion method for the low temperature selective catalytic reduction of NOx with NH3

Jinshuo Qiao; Ning Wang; Zhenhua Wang; Wang Sun; Kening Sun

doi:10.1016/j.catcom.2015.09.023

Porous bimetallic Mn₂Co₁O_x catalysts prepared by a one-step combustion method for the low temperature selective catalytic reduction of NO_x with NH₃

Jinshuo Qiao, Ning Wang, Zhenhua Wang, Wang Sun, Kening Sun^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

The porousMn₂Co₁Ox catalysts are prepared by a one-step combustion (CB) method for lowtemperature deNOx process. This catalyst displays an excellentNH₃-SCR activity, achieving 100%NO_x conversion at 150-300 °C. In addition, the catalyst shows high N₂ selectivity, wide operating temperature window, high stability, and high H₂O and SO₂ resistance. The crystalline phase of CoMn₂O₄, porous structure and large specific surface areaare benefi- cial for the deNOx activity. The catalyst exists abundant Mn⁴⁺, Co³⁺ and surface adsorbed oxygen species, which improve the catalyst's redox ability. Plenty of acid sites fromthe strong interaction ofmanganese and cobalt oxide enhance the catalyst performance.

Original language	English
Pages (from-to)	111-115
Number of pages	5
Journal	Catalysis Communications
Volume	72
DOIs	https://doi.org/10.1016/j.catcom.2015.09.023
Publication status	Published - 5 Dec 2015

Keywords

Combustion method
MnCoO
NO
Porous
SCR

Access to Document

10.1016/j.catcom.2015.09.023

Cite this

@article{52a47134c17244b5ae0059c065a15e42,

title = "Porous bimetallic Mn2Co1Ox catalysts prepared by a one-step combustion method for the low temperature selective catalytic reduction of NOx with NH3",

abstract = "The porousMn2Co1Ox catalysts are prepared by a one-step combustion (CB) method for lowtemperature deNOx process. This catalyst displays an excellentNH3-SCR activity, achieving 100%NOx conversion at 150-300 °C. In addition, the catalyst shows high N2 selectivity, wide operating temperature window, high stability, and high H2O and SO2 resistance. The crystalline phase of CoMn2O4, porous structure and large specific surface areaare benefi- cial for the deNOx activity. The catalyst exists abundant Mn4+, Co3+ and surface adsorbed oxygen species, which improve the catalyst's redox ability. Plenty of acid sites fromthe strong interaction ofmanganese and cobalt oxide enhance the catalyst performance.",

keywords = "Combustion method, MnCoO, NO, Porous, SCR",

author = "Jinshuo Qiao and Ning Wang and Zhenhua Wang and Wang Sun and Kening Sun",

year = "2015",

month = dec,

day = "5",

doi = "10.1016/j.catcom.2015.09.023",

language = "English",

volume = "72",

pages = "111--115",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Porous bimetallic Mn2Co1Ox catalysts prepared by a one-step combustion method for the low temperature selective catalytic reduction of NOx with NH3

AU - Qiao, Jinshuo

AU - Wang, Ning

AU - Wang, Zhenhua

AU - Sun, Wang

AU - Sun, Kening

PY - 2015/12/5

Y1 - 2015/12/5

N2 - The porousMn2Co1Ox catalysts are prepared by a one-step combustion (CB) method for lowtemperature deNOx process. This catalyst displays an excellentNH3-SCR activity, achieving 100%NOx conversion at 150-300 °C. In addition, the catalyst shows high N2 selectivity, wide operating temperature window, high stability, and high H2O and SO2 resistance. The crystalline phase of CoMn2O4, porous structure and large specific surface areaare benefi- cial for the deNOx activity. The catalyst exists abundant Mn4+, Co3+ and surface adsorbed oxygen species, which improve the catalyst's redox ability. Plenty of acid sites fromthe strong interaction ofmanganese and cobalt oxide enhance the catalyst performance.

AB - The porousMn2Co1Ox catalysts are prepared by a one-step combustion (CB) method for lowtemperature deNOx process. This catalyst displays an excellentNH3-SCR activity, achieving 100%NOx conversion at 150-300 °C. In addition, the catalyst shows high N2 selectivity, wide operating temperature window, high stability, and high H2O and SO2 resistance. The crystalline phase of CoMn2O4, porous structure and large specific surface areaare benefi- cial for the deNOx activity. The catalyst exists abundant Mn4+, Co3+ and surface adsorbed oxygen species, which improve the catalyst's redox ability. Plenty of acid sites fromthe strong interaction ofmanganese and cobalt oxide enhance the catalyst performance.

KW - Combustion method

KW - MnCoO

KW - NO

KW - Porous

KW - SCR

UR - http://www.scopus.com/inward/record.url?scp=84942890860&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2015.09.023

DO - 10.1016/j.catcom.2015.09.023

M3 - Article

AN - SCOPUS:84942890860

SN - 1566-7367

VL - 72

SP - 111

EP - 115

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Porous bimetallic Mn₂Co₁O_x catalysts prepared by a one-step combustion method for the low temperature selective catalytic reduction of NO_x with NH₃

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this