Polyether-phosphinite for one-phase catalysis coupled with two-phase separation

Yan Hua Wang; Xiao Zhong Liu; Cui Ying Jia; Zi Lin Jin

Polyether-phosphinite for one-phase catalysis coupled with two-phase separation

Yan Hua Wang^*, Xiao Zhong Liu, Cui Ying Jia, Zi Lin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.

Original language	English
Pages (from-to)	468-471
Number of pages	4
Journal	Chinese Chemical Letters
Volume	13
Issue number	5
Publication status	Published - May 2002
Externally published	Yes

Keywords

Catalyst separation
Higher olefins
Hydroformylation
Phosphinite

Cite this

Wang, Y. H., Liu, X. Z., Jia, C. Y., & Jin, Z. L. (2002). Polyether-phosphinite for one-phase catalysis coupled with two-phase separation. Chinese Chemical Letters, 13(5), 468-471.

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title = "Polyether-phosphinite for one-phase catalysis coupled with two-phase separation",

abstract = "Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.",

keywords = "Catalyst separation, Higher olefins, Hydroformylation, Phosphinite",

author = "Wang, {Yan Hua} and Liu, {Xiao Zhong} and Jia, {Cui Ying} and Jin, {Zi Lin}",

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T1 - Polyether-phosphinite for one-phase catalysis coupled with two-phase separation

AU - Wang, Yan Hua

AU - Liu, Xiao Zhong

AU - Jia, Cui Ying

AU - Jin, Zi Lin

PY - 2002/5

Y1 - 2002/5

N2 - Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.

AB - Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.

KW - Catalyst separation

KW - Higher olefins

KW - Hydroformylation

KW - Phosphinite

UR - http://www.scopus.com/inward/record.url?scp=0036000636&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0036000636

SN - 1001-8417

VL - 13

SP - 468

EP - 471

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 5

ER -

Polyether-phosphinite for one-phase catalysis coupled with two-phase separation

Abstract

Keywords

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