Planar quinary cluster inside a fullerene cage: Synthesis and structural characterizations of Sc3NC@C80-Ih

Tai Shan Wang; Lai Feng; Jing Yi Wu; Wei Xu; Jun Feng Xiang; Kai Tan; Yi Han Ma; Jun Peng Zheng; Li Jiang; Xin Lu; Chun Ying Shu; Chun Ru Wang

doi:10.1021/ja107843b

Planar quinary cluster inside a fullerene cage: Synthesis and structural characterizations of Sc₃NC@C₈₀-I_h

Tai Shan Wang, Lai Feng, Jing Yi Wu, Wei Xu, Jun Feng Xiang, Kai Tan, Yi Han Ma, Jun Peng Zheng, Li Jiang, Xin Lu^*, Chun Ying Shu, Chun Ru Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

140 Citations (Scopus)

Abstract

The endohedral fullerene Sc₃NC@C₈₀-I_h has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)^3- trianion has been disclosed. The fascinating intramolecular dynamics in Sc₃NC@C₈₀-I _h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.

Original language	English
Pages (from-to)	16362-16364
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	46
DOIs	https://doi.org/10.1021/ja107843b
Publication status	Published - 24 Nov 2010
Externally published	Yes

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title = "Planar quinary cluster inside a fullerene cage: Synthesis and structural characterizations of Sc3NC@C80-Ih",

abstract = "The endohedral fullerene Sc3NC@C80-Ih has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)3- trianion has been disclosed. The fascinating intramolecular dynamics in Sc3NC@C80-I h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.",

author = "Wang, {Tai Shan} and Lai Feng and Wu, {Jing Yi} and Wei Xu and Xiang, {Jun Feng} and Kai Tan and Ma, {Yi Han} and Zheng, {Jun Peng} and Li Jiang and Xin Lu and Shu, {Chun Ying} and Wang, {Chun Ru}",

year = "2010",

month = nov,

day = "24",

doi = "10.1021/ja107843b",

language = "English",

volume = "132",

pages = "16362--16364",

journal = "Journal of the American Chemical Society",

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T1 - Planar quinary cluster inside a fullerene cage

T2 - Synthesis and structural characterizations of Sc3NC@C80-Ih

AU - Wang, Tai Shan

AU - Feng, Lai

AU - Wu, Jing Yi

AU - Xu, Wei

AU - Xiang, Jun Feng

AU - Tan, Kai

AU - Ma, Yi Han

AU - Zheng, Jun Peng

AU - Jiang, Li

AU - Lu, Xin

AU - Shu, Chun Ying

AU - Wang, Chun Ru

PY - 2010/11/24

Y1 - 2010/11/24

N2 - The endohedral fullerene Sc3NC@C80-Ih has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)3- trianion has been disclosed. The fascinating intramolecular dynamics in Sc3NC@C80-I h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.

AB - The endohedral fullerene Sc3NC@C80-Ih has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)3- trianion has been disclosed. The fascinating intramolecular dynamics in Sc3NC@C80-I h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.

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DO - 10.1021/ja107843b

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AN - SCOPUS:78649292316

SN - 0002-7863

VL - 132

SP - 16362

EP - 16364

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 46

ER -

Planar quinary cluster inside a fullerene cage: Synthesis and structural characterizations of Sc₃NC@C₈₀-I_h

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