PH-value-controlled assembly of photoluminescent zinc coordination polymers

You Fu Zhou; Ben Yong Lou; Da Qiang Yuan; Yan Qing Xu; Fei Long Jiang; Mao Chun Hong

doi:10.1016/j.ica.2005.03.041

PH-value-controlled assembly of photoluminescent zinc coordination polymers

You Fu Zhou, Ben Yong Lou, Da Qiang Yuan, Yan Qing Xu, Fei Long Jiang, Mao Chun Hong^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

By pH-value adjustment, the reactions of zinc salt, 1,3,5- benzenetricarboxylic acid (H₃btc) and 4,4′-bipyridine (bpy) yield three coordination polymers, formulated as [Zn₃(btc) ₂(bpy)(H₂O)₂]_n (1), [Zn(Hbtc)(bpy)(H₂O)]_n • 3nH₂O (2) and [Zn(Hbtc)(bpy)(H₂O)]_n • 4nH₂O (3), respectively. The structure of 1 is a 3D network containing channels filled with bpy ligands. Compound 2 consists of twofold interpenetrating (10,3)-b networks, while compound 3 is a 2D layer structure. The fluorescent studies reveal that they exhibit intense violet luminescence in solid state.

Original language	English
Pages (from-to)	3057-3064
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	358
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2005.03.041
Publication status	Published - 1 Jul 2005
Externally published	Yes

Keywords

Coordination polymer
Hydrogen bonding
Hydrothermal synthesis
Mixed ligands
Zinc (II) complexes

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10.1016/j.ica.2005.03.041

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title = "PH-value-controlled assembly of photoluminescent zinc coordination polymers",

abstract = "By pH-value adjustment, the reactions of zinc salt, 1,3,5- benzenetricarboxylic acid (H3btc) and 4,4′-bipyridine (bpy) yield three coordination polymers, formulated as [Zn3(btc) 2(bpy)(H2O)2]n (1), [Zn(Hbtc)(bpy)(H2O)]n • 3nH2O (2) and [Zn(Hbtc)(bpy)(H2O)]n • 4nH2O (3), respectively. The structure of 1 is a 3D network containing channels filled with bpy ligands. Compound 2 consists of twofold interpenetrating (10,3)-b networks, while compound 3 is a 2D layer structure. The fluorescent studies reveal that they exhibit intense violet luminescence in solid state.",

keywords = "Coordination polymer, Hydrogen bonding, Hydrothermal synthesis, Mixed ligands, Zinc (II) complexes",

author = "Zhou, {You Fu} and Lou, {Ben Yong} and Yuan, {Da Qiang} and Xu, {Yan Qing} and Jiang, {Fei Long} and Hong, {Mao Chun}",

year = "2005",

month = jul,

day = "1",

doi = "10.1016/j.ica.2005.03.041",

language = "English",

volume = "358",

pages = "3057--3064",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "11",

}

TY - JOUR

T1 - PH-value-controlled assembly of photoluminescent zinc coordination polymers

AU - Zhou, You Fu

AU - Lou, Ben Yong

AU - Yuan, Da Qiang

AU - Xu, Yan Qing

AU - Jiang, Fei Long

AU - Hong, Mao Chun

PY - 2005/7/1

Y1 - 2005/7/1

N2 - By pH-value adjustment, the reactions of zinc salt, 1,3,5- benzenetricarboxylic acid (H3btc) and 4,4′-bipyridine (bpy) yield three coordination polymers, formulated as [Zn3(btc) 2(bpy)(H2O)2]n (1), [Zn(Hbtc)(bpy)(H2O)]n • 3nH2O (2) and [Zn(Hbtc)(bpy)(H2O)]n • 4nH2O (3), respectively. The structure of 1 is a 3D network containing channels filled with bpy ligands. Compound 2 consists of twofold interpenetrating (10,3)-b networks, while compound 3 is a 2D layer structure. The fluorescent studies reveal that they exhibit intense violet luminescence in solid state.

AB - By pH-value adjustment, the reactions of zinc salt, 1,3,5- benzenetricarboxylic acid (H3btc) and 4,4′-bipyridine (bpy) yield three coordination polymers, formulated as [Zn3(btc) 2(bpy)(H2O)2]n (1), [Zn(Hbtc)(bpy)(H2O)]n • 3nH2O (2) and [Zn(Hbtc)(bpy)(H2O)]n • 4nH2O (3), respectively. The structure of 1 is a 3D network containing channels filled with bpy ligands. Compound 2 consists of twofold interpenetrating (10,3)-b networks, while compound 3 is a 2D layer structure. The fluorescent studies reveal that they exhibit intense violet luminescence in solid state.

KW - Coordination polymer

KW - Hydrogen bonding

KW - Hydrothermal synthesis

KW - Mixed ligands

KW - Zinc (II) complexes

UR - http://www.scopus.com/inward/record.url?scp=20144376369&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2005.03.041

DO - 10.1016/j.ica.2005.03.041

M3 - Article

AN - SCOPUS:20144376369

SN - 0020-1693

VL - 358

SP - 3057

EP - 3064

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 11

ER -

PH-value-controlled assembly of photoluminescent zinc coordination polymers

Abstract

Keywords

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