Pd/Zn(OTf)2 Co-Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen

Yang Gao; Fan Yang; Dongdong Pu; Ronibala Devi Laishram; Ruifeng Fan; Guoli Shen; Xuexin Zhang; Jingchao Chen; Baomin Fan

doi:10.1002/ejoc.201801123

Pd/Zn(OTf)₂ Co-Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen

Yang Gao, Fan Yang, Dongdong Pu, Ronibala Devi Laishram^*, Ruifeng Fan, Guoli Shen, Xuexin Zhang, Jingchao Chen, Baomin Fan

^*Corresponding author for this work

Yunnan Minzu University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

An efficient method for the asymmetric hydrogenation of cyclic and acyclic N-sulfonylimines co-catalyzed by Pd/Zn(OTf)₂ using hydrogen gas under ambient pressure was developed. The methodology offers an easy access to generate chiral sulfonylamines in good yields and excellent enantioselectivities.

Original language	English
Pages (from-to)	6274-6279
Number of pages	6
Journal	European Journal of Organic Chemistry
Volume	2018
Issue number	45
DOIs	https://doi.org/10.1002/ejoc.201801123
Publication status	Published - 6 Dec 2018
Externally published	Yes

Keywords

Asymmetric synthesis
Homogeneous catalysis
Hydrogenation
Imine
Palladium

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10.1002/ejoc.201801123

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title = "Pd/Zn(OTf)2 Co-Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen",

abstract = "An efficient method for the asymmetric hydrogenation of cyclic and acyclic N-sulfonylimines co-catalyzed by Pd/Zn(OTf)2 using hydrogen gas under ambient pressure was developed. The methodology offers an easy access to generate chiral sulfonylamines in good yields and excellent enantioselectivities.",

keywords = "Asymmetric synthesis, Homogeneous catalysis, Hydrogenation, Imine, Palladium",

author = "Yang Gao and Fan Yang and Dongdong Pu and Laishram, {Ronibala Devi} and Ruifeng Fan and Guoli Shen and Xuexin Zhang and Jingchao Chen and Baomin Fan",

note = "Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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doi = "10.1002/ejoc.201801123",

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TY - JOUR

T1 - Pd/Zn(OTf)2 Co-Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen

AU - Gao, Yang

AU - Yang, Fan

AU - Pu, Dongdong

AU - Laishram, Ronibala Devi

AU - Fan, Ruifeng

AU - Shen, Guoli

AU - Zhang, Xuexin

AU - Chen, Jingchao

AU - Fan, Baomin

PY - 2018/12/6

Y1 - 2018/12/6

N2 - An efficient method for the asymmetric hydrogenation of cyclic and acyclic N-sulfonylimines co-catalyzed by Pd/Zn(OTf)2 using hydrogen gas under ambient pressure was developed. The methodology offers an easy access to generate chiral sulfonylamines in good yields and excellent enantioselectivities.

AB - An efficient method for the asymmetric hydrogenation of cyclic and acyclic N-sulfonylimines co-catalyzed by Pd/Zn(OTf)2 using hydrogen gas under ambient pressure was developed. The methodology offers an easy access to generate chiral sulfonylamines in good yields and excellent enantioselectivities.

KW - Asymmetric synthesis

KW - Homogeneous catalysis

KW - Hydrogenation

KW - Imine

KW - Palladium

UR - http://www.scopus.com/inward/record.url?scp=85056388675&partnerID=8YFLogxK

U2 - 10.1002/ejoc.201801123

DO - 10.1002/ejoc.201801123

M3 - Article

AN - SCOPUS:85056388675

SN - 1434-193X

VL - 2018

SP - 6274

EP - 6279

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 45

ER -

Pd/Zn(OTf)₂ Co-Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen

Abstract

Keywords

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