Palladium-catalyzed regioselective ortho-acylation of azoxybenzenes with aldehyde derivatives

Meng Sun; Le Kai Hou; Xiang Xiang Chen; Xiao Juan Yang; Wei Sun; Yu Shi Zang

doi:10.1002/adsc.201400594

Palladium-catalyzed regioselective ortho-acylation of azoxybenzenes with aldehyde derivatives

Meng Sun^*, Le Kai Hou, Xiang Xiang Chen, Xiao Juan Yang, Wei Sun, Yu Shi Zang

^*Corresponding author for this work

Northwest University China

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

An efficient strategy for the regioselective ortho-acylation of azoxybenzenes with various aldehydes in the presence of palladium catalysts has been developed and furnishes good to excellent yields. The reaction proceeds smoothly and can tolerate a variety of functional groups.

Original language	English
Pages (from-to)	3789-3793
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	356
Issue number	18
DOIs	https://doi.org/10.1002/adsc.201400594
Publication status	Published - 15 Dec 2014
Externally published	Yes

Keywords

Aldehydes
Azoxybenzenes
C-H bond cleavage
Ortho-acylation
Palladium catalysis

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10.1002/adsc.201400594

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abstract = "An efficient strategy for the regioselective ortho-acylation of azoxybenzenes with various aldehydes in the presence of palladium catalysts has been developed and furnishes good to excellent yields. The reaction proceeds smoothly and can tolerate a variety of functional groups.",

keywords = "Aldehydes, Azoxybenzenes, C-H bond cleavage, Ortho-acylation, Palladium catalysis",

author = "Meng Sun and Hou, {Le Kai} and Chen, {Xiang Xiang} and Yang, {Xiao Juan} and Wei Sun and Zang, {Yu Shi}",

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AU - Sun, Meng

AU - Hou, Le Kai

AU - Chen, Xiang Xiang

AU - Yang, Xiao Juan

AU - Sun, Wei

AU - Zang, Yu Shi

PY - 2014/12/15

Y1 - 2014/12/15

N2 - An efficient strategy for the regioselective ortho-acylation of azoxybenzenes with various aldehydes in the presence of palladium catalysts has been developed and furnishes good to excellent yields. The reaction proceeds smoothly and can tolerate a variety of functional groups.

AB - An efficient strategy for the regioselective ortho-acylation of azoxybenzenes with various aldehydes in the presence of palladium catalysts has been developed and furnishes good to excellent yields. The reaction proceeds smoothly and can tolerate a variety of functional groups.

KW - Aldehydes

KW - Azoxybenzenes

KW - C-H bond cleavage

KW - Ortho-acylation

KW - Palladium catalysis

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DO - 10.1002/adsc.201400594

M3 - Article

AN - SCOPUS:84920797527

SN - 1615-4150

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EP - 3793

JO - Advanced Synthesis and Catalysis

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IS - 18

ER -

Palladium-catalyzed regioselective ortho-acylation of azoxybenzenes with aldehyde derivatives

Abstract

Keywords

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