Palladium-catalyzed regio-selective oxidative C-H bond acylation of azoxybenzenes with alcohols

Lekai Hou; Xiangxiang Chen; Shuang Li; Suxian Cai; Yanxia Zhao; Meng Sun; Xiao Juan Yang

doi:10.1039/c5ob00089k

Palladium-catalyzed regio-selective oxidative C-H bond acylation of azoxybenzenes with alcohols

Lekai Hou, Xiangxiang Chen, Shuang Li, Suxian Cai, Yanxia Zhao, Meng Sun^*, Xiao Juan Yang

^*Corresponding author for this work

Northwest University China

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A palladium-catalyzed regio-selective acylation of C-H bonds of azoxybenzenes with alcohols was developed using tert-butyl hydroperoxide (TBHP) as an oxidant. Alcohol derivatives can act as effective acyl precursors in situ, which are less toxic, inexpensive, stable, and commercially available. These transformations proceeded smoothly and could tolerate a variety of functional groups.

Original language	English
Pages (from-to)	4160-4164
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	14
DOIs	https://doi.org/10.1039/c5ob00089k
Publication status	Published - 14 Apr 2015
Externally published	Yes

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abstract = "A palladium-catalyzed regio-selective acylation of C-H bonds of azoxybenzenes with alcohols was developed using tert-butyl hydroperoxide (TBHP) as an oxidant. Alcohol derivatives can act as effective acyl precursors in situ, which are less toxic, inexpensive, stable, and commercially available. These transformations proceeded smoothly and could tolerate a variety of functional groups.",

author = "Lekai Hou and Xiangxiang Chen and Shuang Li and Suxian Cai and Yanxia Zhao and Meng Sun and Yang, {Xiao Juan}",

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AU - Hou, Lekai

AU - Chen, Xiangxiang

AU - Li, Shuang

AU - Cai, Suxian

AU - Zhao, Yanxia

AU - Sun, Meng

AU - Yang, Xiao Juan

PY - 2015/4/14

Y1 - 2015/4/14

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AB - A palladium-catalyzed regio-selective acylation of C-H bonds of azoxybenzenes with alcohols was developed using tert-butyl hydroperoxide (TBHP) as an oxidant. Alcohol derivatives can act as effective acyl precursors in situ, which are less toxic, inexpensive, stable, and commercially available. These transformations proceeded smoothly and could tolerate a variety of functional groups.

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M3 - Article

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JO - Organic and Biomolecular Chemistry

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Palladium-catalyzed regio-selective oxidative C-H bond acylation of azoxybenzenes with alcohols

Abstract

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