Organic light-emitting diodes with improved hole-electron balance by using molecular layers of phthalocyanine to modify the anode surface

S. Wang, Y. Q. Liu*, X. B. Huang, S. L. Xu, J. R. Gong, X. H. Chen, L. Yi, Y. Xu, G. Yu, L. J. Wan, C. L. Bai, D. B. Zhu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

By using the Langmuir-Blodgett (LB) technique, well-defined molecular layers of 2,9,16-tri(tert-butyl)-23-(10-hydroxydecyloxy)phthalocyanine were fabricated. These LB films have been employed to modify an anode surface of organic light-emitting devices. The insertion of LB films between an indium tin oxide (ITO) and hole-transport layers leads to an increase in device efficiency as a result of an improvement of the balanced carrier injection. An external quantum efficiency of 0.88% and a brightness of 10840 cd/m2 for a device with a structure of ITO/two LB layers/N, N′-diphenyl-N, N′-bis(3-methylphenyl)-1,1′-biphenyl-4,4′-diamine (TPD)/tris(8-hydroquinolinato)aluminium (Alq3)/Al were obtained, while the external quantum efficiency and brightness for the device without LB layers of ITO/TPD/Alq3/Al were 0.51% and 5744 cd/m2, respectively.

Original languageEnglish
Pages (from-to)553-556
Number of pages4
JournalApplied Physics A: Materials Science and Processing
Volume78
Issue number4
DOIs
Publication statusPublished - Mar 2004
Externally publishedYes

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