One-dimensional Mn(III) coordination polymer exhibiting ferromagnetic coupling

Hui Zhong Kou; Yi Tong Wang; Wang Xi Luo; Qi Wei Xie; Jun Tao; Ai Li Cui; De Zhong Shen

doi:10.1021/cg800560x

One-dimensional Mn(III) coordination polymer exhibiting ferromagnetic coupling

Hui Zhong Kou^*, Yi Tong Wang, Wang Xi Luo, Qi Wei Xie, Jun Tao, Ai Li Cui, De Zhong Shen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Mn(III) complexes of 1-(2-hydroxybenzamido)-2-((2-hydroxy-3- methoxybenzylidene)amino)ethane (H₃L), mononuclear [Mn(L)(MeOH)(H₂O)] (1) and amido-bridged one-dimensional [Mn(L)(H₂O)]_∞ (2), have been synthesized by the reaction of MnAc₃ · 2H₂O with H₃L. Magnetic studies revealed that complex 2 exhibits intermetallic ferromagnetic coupling, which is the first one-dimensional high-spin Mn(III) complex with ferromagnetic behavior.

Original language	English
Pages (from-to)	3908-3910
Number of pages	3
Journal	Crystal Growth and Design
Volume	8
Issue number	11
DOIs	https://doi.org/10.1021/cg800560x
Publication status	Published - Nov 2008
Externally published	Yes

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title = "One-dimensional Mn(III) coordination polymer exhibiting ferromagnetic coupling",

abstract = "Mn(III) complexes of 1-(2-hydroxybenzamido)-2-((2-hydroxy-3- methoxybenzylidene)amino)ethane (H3L), mononuclear [Mn(L)(MeOH)(H2O)] (1) and amido-bridged one-dimensional [Mn(L)(H2O)]∞ (2), have been synthesized by the reaction of MnAc3 · 2H2O with H3L. Magnetic studies revealed that complex 2 exhibits intermetallic ferromagnetic coupling, which is the first one-dimensional high-spin Mn(III) complex with ferromagnetic behavior.",

author = "Kou, {Hui Zhong} and Wang, {Yi Tong} and Luo, {Wang Xi} and Xie, {Qi Wei} and Jun Tao and Cui, {Ai Li} and Shen, {De Zhong}",

year = "2008",

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doi = "10.1021/cg800560x",

language = "English",

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publisher = "American Chemical Society",

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T1 - One-dimensional Mn(III) coordination polymer exhibiting ferromagnetic coupling

AU - Kou, Hui Zhong

AU - Wang, Yi Tong

AU - Luo, Wang Xi

AU - Xie, Qi Wei

AU - Tao, Jun

AU - Cui, Ai Li

AU - Shen, De Zhong

PY - 2008/11

Y1 - 2008/11

N2 - Mn(III) complexes of 1-(2-hydroxybenzamido)-2-((2-hydroxy-3- methoxybenzylidene)amino)ethane (H3L), mononuclear [Mn(L)(MeOH)(H2O)] (1) and amido-bridged one-dimensional [Mn(L)(H2O)]∞ (2), have been synthesized by the reaction of MnAc3 · 2H2O with H3L. Magnetic studies revealed that complex 2 exhibits intermetallic ferromagnetic coupling, which is the first one-dimensional high-spin Mn(III) complex with ferromagnetic behavior.

AB - Mn(III) complexes of 1-(2-hydroxybenzamido)-2-((2-hydroxy-3- methoxybenzylidene)amino)ethane (H3L), mononuclear [Mn(L)(MeOH)(H2O)] (1) and amido-bridged one-dimensional [Mn(L)(H2O)]∞ (2), have been synthesized by the reaction of MnAc3 · 2H2O with H3L. Magnetic studies revealed that complex 2 exhibits intermetallic ferromagnetic coupling, which is the first one-dimensional high-spin Mn(III) complex with ferromagnetic behavior.

UR - http://www.scopus.com/inward/record.url?scp=61549129270&partnerID=8YFLogxK

U2 - 10.1021/cg800560x

DO - 10.1021/cg800560x

M3 - Article

AN - SCOPUS:61549129270

SN - 1528-7483

VL - 8

SP - 3908

EP - 3910

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 11

ER -

One-dimensional Mn(III) coordination polymer exhibiting ferromagnetic coupling

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