O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

Yang Yang; Yang Yang; Yumin Qian; Haijing Li; Zhenhua Zhang; Yuewen Mu; David Do; Bo Zhou; Jing Dong; Wenjun Yan; Yong Qin; Li Fang; Renfei Feng; Jigang Zhou; Peng Zhang; Juncai Dong; Guihua Yu; Yuanyue Liu; Xianming Zhang; Xianming Zhang; Xiujun Fan; Xiujun Fan

doi:10.1126/sciadv.aba6586

O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

Yang Yang, Yang Yang, Yumin Qian, Haijing Li, Zhenhua Zhang, Yuewen Mu, David Do, Bo Zhou, Jing Dong, Wenjun Yan, Yong Qin, Li Fang, Renfei Feng, Jigang Zhou, Peng Zhang, Juncai Dong, Guihua Yu, Yuanyue Liu, Xianming Zhang^*, Xianming Zhang^*Xiujun Fan^*, Xiujun Fan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

259 Citations (Scopus)

Abstract

Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W1Mo1-NG), which is synthesized by controllable self-assembly and nitridation processes. In W1Mo1-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through oxygen atoms with W-O-Mo-O-C configuration, resulting in stable and finely distribution. The W1Mo1-NG DAC enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte. The electron delocalization of W-O-Mo-O-C configuration provides optimal adsorption strength of H and boosts the HER kinetics, thereby notably promoting the intrinsic activity.

Original language	English
Article number	EABA6586
Journal	Science advances
Volume	6
Issue number	23
DOIs	https://doi.org/10.1126/sciadv.aba6586
Publication status	Published - Jun 2020
Externally published	Yes

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Yang, Y., Yang, Y., Qian, Y., Li, H., Zhang, Z., Mu, Y., Do, D., Zhou, B., Dong, J., Yan, W., Qin, Y., Fang, L., Feng, R., Zhou, J., Zhang, P., Dong, J., Yu, G., Liu, Y., Zhang, X., ... Fan, X. (2020). O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution. Science advances, 6(23), Article EABA6586. https://doi.org/10.1126/sciadv.aba6586

@article{9bb4dbde57ae4f2997c4ae429ebf4b48,

title = "O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution",

abstract = "Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W1Mo1-NG), which is synthesized by controllable self-assembly and nitridation processes. In W1Mo1-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through oxygen atoms with W-O-Mo-O-C configuration, resulting in stable and finely distribution. The W1Mo1-NG DAC enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte. The electron delocalization of W-O-Mo-O-C configuration provides optimal adsorption strength of H and boosts the HER kinetics, thereby notably promoting the intrinsic activity.",

author = "Yang Yang and Yang Yang and Yumin Qian and Haijing Li and Zhenhua Zhang and Yuewen Mu and David Do and Bo Zhou and Jing Dong and Wenjun Yan and Yong Qin and Li Fang and Renfei Feng and Jigang Zhou and Peng Zhang and Juncai Dong and Guihua Yu and Yuanyue Liu and Xianming Zhang and Xianming Zhang and Xiujun Fan and Xiujun Fan",

note = "Publisher Copyright: {\textcopyright} 2020 The Authors.",

year = "2020",

month = jun,

doi = "10.1126/sciadv.aba6586",

language = "English",

volume = "6",

journal = "Science advances",

issn = "2375-2548",

publisher = "American Association for the Advancement of Science",

number = "23",

}

Yang, Y, Yang, Y, Qian, Y, Li, H, Zhang, Z, Mu, Y, Do, D, Zhou, B, Dong, J, Yan, W, Qin, Y, Fang, L, Feng, R, Zhou, J, Zhang, P, Dong, J, Yu, G, Liu, Y, Zhang, X, Zhang, X, Fan, X & Fan, X 2020, 'O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution', Science advances, vol. 6, no. 23, EABA6586. https://doi.org/10.1126/sciadv.aba6586

TY - JOUR

T1 - O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

AU - Yang, Yang

AU - Qian, Yumin

AU - Li, Haijing

AU - Zhang, Zhenhua

AU - Mu, Yuewen

AU - Do, David

AU - Zhou, Bo

AU - Dong, Jing

AU - Yan, Wenjun

AU - Qin, Yong

AU - Fang, Li

AU - Feng, Renfei

AU - Zhou, Jigang

AU - Zhang, Peng

AU - Dong, Juncai

AU - Yu, Guihua

AU - Liu, Yuanyue

AU - Zhang, Xianming

AU - Fan, Xiujun

PY - 2020/6

Y1 - 2020/6

N2 - Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W1Mo1-NG), which is synthesized by controllable self-assembly and nitridation processes. In W1Mo1-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through oxygen atoms with W-O-Mo-O-C configuration, resulting in stable and finely distribution. The W1Mo1-NG DAC enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte. The electron delocalization of W-O-Mo-O-C configuration provides optimal adsorption strength of H and boosts the HER kinetics, thereby notably promoting the intrinsic activity.

AB - Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W1Mo1-NG), which is synthesized by controllable self-assembly and nitridation processes. In W1Mo1-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through oxygen atoms with W-O-Mo-O-C configuration, resulting in stable and finely distribution. The W1Mo1-NG DAC enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte. The electron delocalization of W-O-Mo-O-C configuration provides optimal adsorption strength of H and boosts the HER kinetics, thereby notably promoting the intrinsic activity.

UR - http://www.scopus.com/inward/record.url?scp=85086626899&partnerID=8YFLogxK

U2 - 10.1126/sciadv.aba6586

DO - 10.1126/sciadv.aba6586

M3 - Article

C2 - 32548271

AN - SCOPUS:85086626899

SN - 2375-2548

VL - 6

JO - Science advances

JF - Science advances

IS - 23

M1 - EABA6586

ER -

O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

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