TY - JOUR
T1 - Novel concept of nano-additive design
T2 - PTFE@silica Janus nanoparticles for water lubrication
AU - Liu, Yanfei
AU - He, Hailing
AU - Yang, Meng
AU - Zhang, Ruize
AU - Yu, Shengtao
AU - Yang, Tiantian
AU - Wang, Wenzhong
AU - Liang, Fuxin
N1 - Publisher Copyright:
© 2023, The author(s).
PY - 2024/2
Y1 - 2024/2
N2 - Polytetrafluoroethylene (PTFE) has been widely used as a lubrication additive for reducing friction and wear; however, the hydrophobic nature of PTFE restricts its application in eco-friendly water-based lubrication systems. In this study, for the first time, we designed novel PTFE@silica Janus nanoparticles (JNs) to meet the requirement for additives in water-based lubricants, which have excellent dispersion stability in water attributed to the unique amphiphilic structure. By introducing the lubrication of the aqueous dispersion of the JNs with a concentration of 0.5 wt%, the coefficient of friction (COF) and wear volume were reduced by 63.8% and 94.2%, respectively, comparing to those with the lubrication of pure water. Meanwhile, the JNs suspension also exhibits better lubrication and wear-resistance performances comparing to commercial silica and PTFE suspensions. The excellent tribological behaviors of PTFE@silica JNs as nano-additives could be attributed to the synergetic effect of the two components, where the PTFE provided lubrication through the formed tribofilms on the friction pairs, and the rigid silica further enhanced the wear-resistance performance. Most importantly, the unique structure of JNs makes it possible to use PTFE as an additive in water-lubrication systems. Our study shed light on the design and application of novel JNs nanomaterials as additives to meet the requirements of future industrial applications.[Figure not available: see fulltext.]
AB - Polytetrafluoroethylene (PTFE) has been widely used as a lubrication additive for reducing friction and wear; however, the hydrophobic nature of PTFE restricts its application in eco-friendly water-based lubrication systems. In this study, for the first time, we designed novel PTFE@silica Janus nanoparticles (JNs) to meet the requirement for additives in water-based lubricants, which have excellent dispersion stability in water attributed to the unique amphiphilic structure. By introducing the lubrication of the aqueous dispersion of the JNs with a concentration of 0.5 wt%, the coefficient of friction (COF) and wear volume were reduced by 63.8% and 94.2%, respectively, comparing to those with the lubrication of pure water. Meanwhile, the JNs suspension also exhibits better lubrication and wear-resistance performances comparing to commercial silica and PTFE suspensions. The excellent tribological behaviors of PTFE@silica JNs as nano-additives could be attributed to the synergetic effect of the two components, where the PTFE provided lubrication through the formed tribofilms on the friction pairs, and the rigid silica further enhanced the wear-resistance performance. Most importantly, the unique structure of JNs makes it possible to use PTFE as an additive in water-lubrication systems. Our study shed light on the design and application of novel JNs nanomaterials as additives to meet the requirements of future industrial applications.[Figure not available: see fulltext.]
KW - Janus nanoparticles (JNs)
KW - friction
KW - lubrication
KW - nano-additives
KW - polytetrafluoroethylene (PTFE)
UR - http://www.scopus.com/inward/record.url?scp=85159068947&partnerID=8YFLogxK
U2 - 10.1007/s40544-023-0749-3
DO - 10.1007/s40544-023-0749-3
M3 - Article
AN - SCOPUS:85159068947
SN - 2223-7690
VL - 12
SP - 258
EP - 270
JO - Friction
JF - Friction
IS - 2
ER -