Nested core-shell electrosprayed microspheres: A potential assembly with synergetic interface for energy release

Tao Yan; Hui Ren; Jie Liu; Yapeng Ou; Qingjie Jiao

doi:10.1016/j.matlet.2019.01.082

Nested core-shell electrosprayed microspheres: A potential assembly with synergetic interface for energy release

Tao Yan, Hui Ren^*, Jie Liu, Yapeng Ou, Qingjie Jiao

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In this study, nano-aluminum (nAl)/1,3,5-trinitro-1,3,5-triazacyclohexane (RDX)/nitrocellulose (NC) nested core-shell microspheres were fabricated by the coaxial-electrospray technique. The investigations on morphology properties and chemical heterogeneity demonstrate that RDX is integrated with nAl particles coated by NC utilizing the nested core-shell structure. The structure contributed to the improvement of combustion heat and laser ignition sensitivity of electrosprayed nAl/RDX/NC microspheres. Characteristic thermal behaviors were also produced due to the multi-layer structure. Analysis of the flame radiative intensity suggests that ignition properties of the microspheres could be attributed to the synergetic interface, which enhances thermal and mass transmission between each component and then reduces ignition delay.

Original language	English
Pages (from-to)	92-95
Number of pages	4
Journal	Materials Letters
Volume	241
DOIs	https://doi.org/10.1016/j.matlet.2019.01.082
Publication status	Published - 15 Apr 2019

Keywords

AFM-IR
Energy release
Interfaces
Nanoparticles
Nested core-shell microsphere

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10.1016/j.matlet.2019.01.082

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title = "Nested core-shell electrosprayed microspheres: A potential assembly with synergetic interface for energy release",

abstract = "In this study, nano-aluminum (nAl)/1,3,5-trinitro-1,3,5-triazacyclohexane (RDX)/nitrocellulose (NC) nested core-shell microspheres were fabricated by the coaxial-electrospray technique. The investigations on morphology properties and chemical heterogeneity demonstrate that RDX is integrated with nAl particles coated by NC utilizing the nested core-shell structure. The structure contributed to the improvement of combustion heat and laser ignition sensitivity of electrosprayed nAl/RDX/NC microspheres. Characteristic thermal behaviors were also produced due to the multi-layer structure. Analysis of the flame radiative intensity suggests that ignition properties of the microspheres could be attributed to the synergetic interface, which enhances thermal and mass transmission between each component and then reduces ignition delay.",

keywords = "AFM-IR, Energy release, Interfaces, Nanoparticles, Nested core-shell microsphere",

author = "Tao Yan and Hui Ren and Jie Liu and Yapeng Ou and Qingjie Jiao",

note = "Publisher Copyright: {\textcopyright} 2019",

year = "2019",

month = apr,

day = "15",

doi = "10.1016/j.matlet.2019.01.082",

language = "English",

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journal = "Materials Letters",

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TY - JOUR

T1 - Nested core-shell electrosprayed microspheres

T2 - A potential assembly with synergetic interface for energy release

AU - Yan, Tao

AU - Ren, Hui

AU - Liu, Jie

AU - Ou, Yapeng

AU - Jiao, Qingjie

PY - 2019/4/15

Y1 - 2019/4/15

N2 - In this study, nano-aluminum (nAl)/1,3,5-trinitro-1,3,5-triazacyclohexane (RDX)/nitrocellulose (NC) nested core-shell microspheres were fabricated by the coaxial-electrospray technique. The investigations on morphology properties and chemical heterogeneity demonstrate that RDX is integrated with nAl particles coated by NC utilizing the nested core-shell structure. The structure contributed to the improvement of combustion heat and laser ignition sensitivity of electrosprayed nAl/RDX/NC microspheres. Characteristic thermal behaviors were also produced due to the multi-layer structure. Analysis of the flame radiative intensity suggests that ignition properties of the microspheres could be attributed to the synergetic interface, which enhances thermal and mass transmission between each component and then reduces ignition delay.

AB - In this study, nano-aluminum (nAl)/1,3,5-trinitro-1,3,5-triazacyclohexane (RDX)/nitrocellulose (NC) nested core-shell microspheres were fabricated by the coaxial-electrospray technique. The investigations on morphology properties and chemical heterogeneity demonstrate that RDX is integrated with nAl particles coated by NC utilizing the nested core-shell structure. The structure contributed to the improvement of combustion heat and laser ignition sensitivity of electrosprayed nAl/RDX/NC microspheres. Characteristic thermal behaviors were also produced due to the multi-layer structure. Analysis of the flame radiative intensity suggests that ignition properties of the microspheres could be attributed to the synergetic interface, which enhances thermal and mass transmission between each component and then reduces ignition delay.

KW - AFM-IR

KW - Energy release

KW - Interfaces

KW - Nanoparticles

KW - Nested core-shell microsphere

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U2 - 10.1016/j.matlet.2019.01.082

DO - 10.1016/j.matlet.2019.01.082

M3 - Article

AN - SCOPUS:85060499535

SN - 0167-577X

VL - 241

SP - 92

EP - 95

JO - Materials Letters

JF - Materials Letters

ER -

Nested core-shell electrosprayed microspheres: A potential assembly with synergetic interface for energy release

Abstract

Keywords

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