Na3TbSi3O9·3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels

Guangmei Wang; Jiyang Li; Jihong Yu; Peng Chen; Qinhe Pan; Hongwei Song; Ruren Xu

doi:10.1021/cm061578w

Na₃TbSi₃O₉·3H₂O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels

Guangmei Wang, Jiyang Li, Jihong Yu^*, Peng Chen, Qinhe Pan, Hongwei Song, Ruren Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The structure and preparation of a new luminescent microporous terbium silicate Na₃TbSi₃O₉.3H₂O (TbSiO-CJ1) crystallized in the enantiomorphic space group P2₁2 ₁2₁ were analyzed. The structure was featured by a A-Co(en)₃ such as chiral unit of [TbSi₆O₉] and contained helical sechser silicate chains and 9- ring channels. TbSiO-CJI was prepared by the mild hydrothermal reaction of a mixture of fumed silica and water in a 1.0:0.12:8.46:58 molar ratio at 230°C for 6 days in a Teflon lined stainless steel autoclave. The single crystal unit revealed that TbSiO-CJI is composed of a macroanionic [TbSi₃O₉]_3- framework. The Na positive ions residing in the channels compensated the negative charge of the inorganic framework. Results show that a new terbium silicate has been synthesized under mild hydrothermal conditions.

Original language	English
Pages (from-to)	5637-5639
Number of pages	3
Journal	Chemistry of Materials
Volume	18
Issue number	24
DOIs	https://doi.org/10.1021/cm061578w
Publication status	Published - 28 Nov 2006
Externally published	Yes

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title = "Na3TbSi3O9·3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels",

abstract = "The structure and preparation of a new luminescent microporous terbium silicate Na3TbSi3O9.3H2O (TbSiO-CJ1) crystallized in the enantiomorphic space group P212 121 were analyzed. The structure was featured by a A-Co(en)3 such as chiral unit of [TbSi6O9] and contained helical sechser silicate chains and 9- ring channels. TbSiO-CJI was prepared by the mild hydrothermal reaction of a mixture of fumed silica and water in a 1.0:0.12:8.46:58 molar ratio at 230°C for 6 days in a Teflon lined stainless steel autoclave. The single crystal unit revealed that TbSiO-CJI is composed of a macroanionic [TbSi3O9]3- framework. The Na positive ions residing in the channels compensated the negative charge of the inorganic framework. Results show that a new terbium silicate has been synthesized under mild hydrothermal conditions.",

author = "Guangmei Wang and Jiyang Li and Jihong Yu and Peng Chen and Qinhe Pan and Hongwei Song and Ruren Xu",

year = "2006",

month = nov,

day = "28",

doi = "10.1021/cm061578w",

language = "English",

volume = "18",

pages = "5637--5639",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Na3TbSi3O9·3H2O

T2 - A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels

AU - Wang, Guangmei

AU - Li, Jiyang

AU - Yu, Jihong

AU - Chen, Peng

AU - Pan, Qinhe

AU - Song, Hongwei

AU - Xu, Ruren

PY - 2006/11/28

Y1 - 2006/11/28

N2 - The structure and preparation of a new luminescent microporous terbium silicate Na3TbSi3O9.3H2O (TbSiO-CJ1) crystallized in the enantiomorphic space group P212 121 were analyzed. The structure was featured by a A-Co(en)3 such as chiral unit of [TbSi6O9] and contained helical sechser silicate chains and 9- ring channels. TbSiO-CJI was prepared by the mild hydrothermal reaction of a mixture of fumed silica and water in a 1.0:0.12:8.46:58 molar ratio at 230°C for 6 days in a Teflon lined stainless steel autoclave. The single crystal unit revealed that TbSiO-CJI is composed of a macroanionic [TbSi3O9]3- framework. The Na positive ions residing in the channels compensated the negative charge of the inorganic framework. Results show that a new terbium silicate has been synthesized under mild hydrothermal conditions.

AB - The structure and preparation of a new luminescent microporous terbium silicate Na3TbSi3O9.3H2O (TbSiO-CJ1) crystallized in the enantiomorphic space group P212 121 were analyzed. The structure was featured by a A-Co(en)3 such as chiral unit of [TbSi6O9] and contained helical sechser silicate chains and 9- ring channels. TbSiO-CJI was prepared by the mild hydrothermal reaction of a mixture of fumed silica and water in a 1.0:0.12:8.46:58 molar ratio at 230°C for 6 days in a Teflon lined stainless steel autoclave. The single crystal unit revealed that TbSiO-CJI is composed of a macroanionic [TbSi3O9]3- framework. The Na positive ions residing in the channels compensated the negative charge of the inorganic framework. Results show that a new terbium silicate has been synthesized under mild hydrothermal conditions.

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U2 - 10.1021/cm061578w

DO - 10.1021/cm061578w

M3 - Article

AN - SCOPUS:33845424580

SN - 0897-4756

VL - 18

SP - 5637

EP - 5639

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 24

ER -

Na₃TbSi₃O₉·3H₂O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels

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