N, S-doped TiO2 anode effect on performance of dye-sensitized solar cells

J. C. Zhang*, Z. Y. Han, Q. Y. Li, X. Y. Yang, Y. Yu, W. L. Cao

*Corresponding author for this work

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Abstract

The modification of non-metallic elements N and S to nanocrystalline TiO2 anode results in the energy gap is reduced to 2.63 eV and a strong redshift to the visible region occurred in the UVvisible spectrum. Poly (3-decylthiophene) (P3DT) is synthesized. Ultravioletvisible spectra (UVvis) shows that the light absorption of P3DT (Poly (3-decylthiophene)) and N719 (RuL2(NCS)2:2TBA (L=2,2′-bipyridyl-4, 4′-dicarboxylic acid)) are complementary to cover the entire visible region. Solar cell based on NS/TiO2 is co-sensitized by P3DT and N719. The photoelectric conversion efficiency of co-sensitized solar cell increases 56.8% comparing with the single dye-sensitized solar cell.

Original languageEnglish
Pages (from-to)1239-1244
Number of pages6
JournalJournal of Physics and Chemistry of Solids
Volume72
Issue number11
DOIs
Publication statusPublished - Nov 2011
Externally publishedYes

Keywords

  • A. Electronic materials
  • A. Nanostructures
  • A. Polymers
  • C. X-ray diffraction

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Zhang, J. C., Han, Z. Y., Li, Q. Y., Yang, X. Y., Yu, Y., & Cao, W. L. (2011). N, S-doped TiO2 anode effect on performance of dye-sensitized solar cells. Journal of Physics and Chemistry of Solids, 72(11), 1239-1244. https://doi.org/10.1016/j.jpcs.2011.07.014