Metallophilic attractions between d8-d10 heterometallic compounds trans-[Pt(PH3)2(CN)2] and M(PH3)2+ (M=Ag or Cu): Ab initio study

Bao Hui Xia; Hong Xing Zhang; Yu Qiu Jiao; Qing Jiang Pan; Ze Sheng Li; Chia Chung Sun

doi:10.1063/1.1753563

Metallophilic attractions between d⁸-d¹⁰ heterometallic compounds trans-[Pt(PH₃)₂(CN)₂] and M(PH₃)₂⁺ (M=Ag or Cu): Ab initio study

Bao Hui Xia, Hong Xing Zhang^*, Yu Qiu Jiao, Qing Jiang Pan, Ze Sheng Li, Chia Chung Sun

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

Original language	English
Pages (from-to)	11487-11492
Number of pages	6
Journal	Journal of Chemical Physics
Volume	120
Issue number	24
DOIs	https://doi.org/10.1063/1.1753563
Publication status	Published - 22 Jun 2004
Externally published	Yes

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Xia, B. H., Zhang, H. X., Jiao, Y. Q., Pan, Q. J., Li, Z. S., & Sun, C. C. (2004). Metallophilic attractions between d⁸-d¹⁰ heterometallic compounds trans-[Pt(PH₃)₂(CN)₂] and M(PH₃)₂⁺ (M=Ag or Cu): Ab initio study. Journal of Chemical Physics, 120(24), 11487-11492. https://doi.org/10.1063/1.1753563

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abstract = "Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.",

author = "Xia, {Bao Hui} and Zhang, {Hong Xing} and Jiao, {Yu Qiu} and Pan, {Qing Jiang} and Li, {Ze Sheng} and Sun, {Chia Chung}",

year = "2004",

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doi = "10.1063/1.1753563",

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T2 - Ab initio study

AU - Xia, Bao Hui

AU - Zhang, Hong Xing

AU - Jiao, Yu Qiu

AU - Pan, Qing Jiang

AU - Li, Ze Sheng

AU - Sun, Chia Chung

PY - 2004/6/22

Y1 - 2004/6/22

N2 - Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

AB - Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

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DO - 10.1063/1.1753563

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VL - 120

SP - 11487

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JO - Journal of Chemical Physics

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ER -

Metallophilic attractions between d⁸-d¹⁰ heterometallic compounds trans-[Pt(PH₃)₂(CN)₂] and M(PH₃)₂⁺ (M=Ag or Cu): Ab initio study

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