Luminescent single-molecule magnet of metallofullerene DyErScN@Ih-C80

Mingzhe Nie; Jin Xiong; Chong Zhao; Haibing Meng; Kun Zhang; Yibo Han; Jie Li; Bingwu Wang; Lai Feng; Chunru Wang; Taishan Wang

doi:10.1007/s12274-019-2429-1

Luminescent single-molecule magnet of metallofullerene DyErScN@I_h-C₈₀

Mingzhe Nie, Jin Xiong, Chong Zhao, Haibing Meng, Kun Zhang, Yibo Han, Jie Li, Bingwu Wang, Lai Feng, Chunru Wang^*, Taishan Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Magneto-luminescent molecules have significant applications in data storage and quantum computing. However, design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challenging. In this work, we report a metallofullerene DyErScN@I_h-C₈₀ exhibiting single-molecule magnet (SMM) behavior and near-infrared emission. For DyErScN@I_h-C₈₀, two functional lanthanide metal ions of Dy³⁺ (SMM function) and Er³⁺ (luminescent function) are integrated inside a fullerene cage using a trimetallic nitride template, and its structure has been unambiguously characterized by single-crystal X-ray diffraction. Magnetic measurements revealed that DyErScN@I_h-C₈₀ behaves as a SMM with a blocking temperature up to 9 K resulting from the intramolecular magnetic interaction between Dy³⁺ and Er³⁺ ions. Moreover, DyErScN@I_h-C₈₀ exhibits temperature-dependent near-infrared emission around 1.5 μm with multiple splitting peaks from Er³⁺, which arises from the influence of Dy³⁺ ion. This study provides a new strategy to synthesize new magneto-luminescent molecule materials. [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	1727-1731
Number of pages	5
Journal	Nano Research
Volume	12
Issue number	7
DOIs	https://doi.org/10.1007/s12274-019-2429-1
Publication status	Published - 1 Jul 2019
Externally published	Yes

Keywords

metallofullerene
near-infrared photoluminescence
single-molecule magnet

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10.1007/s12274-019-2429-1

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title = "Luminescent single-molecule magnet of metallofullerene DyErScN@Ih-C80",

abstract = "Magneto-luminescent molecules have significant applications in data storage and quantum computing. However, design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challenging. In this work, we report a metallofullerene DyErScN@Ih-C80 exhibiting single-molecule magnet (SMM) behavior and near-infrared emission. For DyErScN@Ih-C80, two functional lanthanide metal ions of Dy3+ (SMM function) and Er3+ (luminescent function) are integrated inside a fullerene cage using a trimetallic nitride template, and its structure has been unambiguously characterized by single-crystal X-ray diffraction. Magnetic measurements revealed that DyErScN@Ih-C80 behaves as a SMM with a blocking temperature up to 9 K resulting from the intramolecular magnetic interaction between Dy3+ and Er3+ ions. Moreover, DyErScN@Ih-C80 exhibits temperature-dependent near-infrared emission around 1.5 μm with multiple splitting peaks from Er3+, which arises from the influence of Dy3+ ion. This study provides a new strategy to synthesize new magneto-luminescent molecule materials. [Figure not available: see fulltext.].",

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T1 - Luminescent single-molecule magnet of metallofullerene DyErScN@Ih-C80

AU - Nie, Mingzhe

AU - Xiong, Jin

AU - Zhao, Chong

AU - Meng, Haibing

AU - Zhang, Kun

AU - Han, Yibo

AU - Li, Jie

AU - Wang, Bingwu

AU - Feng, Lai

AU - Wang, Chunru

AU - Wang, Taishan

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Magneto-luminescent molecules have significant applications in data storage and quantum computing. However, design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challenging. In this work, we report a metallofullerene DyErScN@Ih-C80 exhibiting single-molecule magnet (SMM) behavior and near-infrared emission. For DyErScN@Ih-C80, two functional lanthanide metal ions of Dy3+ (SMM function) and Er3+ (luminescent function) are integrated inside a fullerene cage using a trimetallic nitride template, and its structure has been unambiguously characterized by single-crystal X-ray diffraction. Magnetic measurements revealed that DyErScN@Ih-C80 behaves as a SMM with a blocking temperature up to 9 K resulting from the intramolecular magnetic interaction between Dy3+ and Er3+ ions. Moreover, DyErScN@Ih-C80 exhibits temperature-dependent near-infrared emission around 1.5 μm with multiple splitting peaks from Er3+, which arises from the influence of Dy3+ ion. This study provides a new strategy to synthesize new magneto-luminescent molecule materials. [Figure not available: see fulltext.].

AB - Magneto-luminescent molecules have significant applications in data storage and quantum computing. However, design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challenging. In this work, we report a metallofullerene DyErScN@Ih-C80 exhibiting single-molecule magnet (SMM) behavior and near-infrared emission. For DyErScN@Ih-C80, two functional lanthanide metal ions of Dy3+ (SMM function) and Er3+ (luminescent function) are integrated inside a fullerene cage using a trimetallic nitride template, and its structure has been unambiguously characterized by single-crystal X-ray diffraction. Magnetic measurements revealed that DyErScN@Ih-C80 behaves as a SMM with a blocking temperature up to 9 K resulting from the intramolecular magnetic interaction between Dy3+ and Er3+ ions. Moreover, DyErScN@Ih-C80 exhibits temperature-dependent near-infrared emission around 1.5 μm with multiple splitting peaks from Er3+, which arises from the influence of Dy3+ ion. This study provides a new strategy to synthesize new magneto-luminescent molecule materials. [Figure not available: see fulltext.].

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Luminescent single-molecule magnet of metallofullerene DyErScN@I_h-C₈₀

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