Liquid phase therapy to solid electrolyte–electrode interface in solid-state Li metal batteries: A review

Chen Zi Zhao; Bo Chen Zhao; Chong Yan; Xue Qiang Zhang; Jia Qi Huang; Yifei Mo; Xiaoxiong Xu; Hong Li; Qiang Zhang

doi:10.1016/j.ensm.2019.07.026

Liquid phase therapy to solid electrolyte–electrode interface in solid-state Li metal batteries: A review

Chen Zi Zhao, Bo Chen Zhao, Chong Yan, Xue Qiang Zhang, Jia Qi Huang, Yifei Mo, Xiaoxiong Xu, Hong Li, Qiang Zhang^*

^*Corresponding author for this work

Advanced Research Institute of Multidisciplinary Science

Research output: Contribution to journal › Review article › peer-review

227 Citations (Scopus)

Abstract

Solid-state lithium (Li) metal batteries, employing solid electrolytes, with high energy density and enhanced safety are promising choices for next-generation electrochemical energy storage devices. However, the large interfacial resistances seriously hinder their commercialization. To construct a conformal interface with acceptable resistances, introducing small amounts of additional liquid electrolytes is one of the most convenient and effective solutions. This review summarizes the fundamental understandings on the interfacial behaviors between liquid electrolytes, electrodes and solid-state electrolytes. Afterwards, emerging strategies are discussed, involving interfacial wetting, in situ polymerization and interfacial reactions. Finally, current limitations and perspectives are presented for liquid phase therapy regarding the interfacial science and engineering.

Original language	English
Pages (from-to)	75-84
Number of pages	10
Journal	Energy Storage Materials
Volume	24
DOIs	https://doi.org/10.1016/j.ensm.2019.07.026
Publication status	Published - Jan 2020

Keywords

Electrolyte–electrode interface
Liquid electrolyte
Lithium metal anode
Solid electrolyte interface
Solid-state rechargeable batteries

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ensm.2019.07.026

Cite this

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title = "Liquid phase therapy to solid electrolyte–electrode interface in solid-state Li metal batteries: A review",

abstract = "Solid-state lithium (Li) metal batteries, employing solid electrolytes, with high energy density and enhanced safety are promising choices for next-generation electrochemical energy storage devices. However, the large interfacial resistances seriously hinder their commercialization. To construct a conformal interface with acceptable resistances, introducing small amounts of additional liquid electrolytes is one of the most convenient and effective solutions. This review summarizes the fundamental understandings on the interfacial behaviors between liquid electrolytes, electrodes and solid-state electrolytes. Afterwards, emerging strategies are discussed, involving interfacial wetting, in situ polymerization and interfacial reactions. Finally, current limitations and perspectives are presented for liquid phase therapy regarding the interfacial science and engineering.",

keywords = "Electrolyte–electrode interface, Liquid electrolyte, Lithium metal anode, Solid electrolyte interface, Solid-state rechargeable batteries",

author = "Zhao, {Chen Zi} and Zhao, {Bo Chen} and Chong Yan and Zhang, {Xue Qiang} and Huang, {Jia Qi} and Yifei Mo and Xiaoxiong Xu and Hong Li and Qiang Zhang",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2020",

month = jan,

doi = "10.1016/j.ensm.2019.07.026",

language = "English",

volume = "24",

pages = "75--84",

journal = "Energy Storage Materials",

issn = "2405-8297",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Liquid phase therapy to solid electrolyte–electrode interface in solid-state Li metal batteries

T2 - A review

AU - Zhao, Chen Zi

AU - Zhao, Bo Chen

AU - Yan, Chong

AU - Zhang, Xue Qiang

AU - Huang, Jia Qi

AU - Mo, Yifei

AU - Xu, Xiaoxiong

AU - Li, Hong

AU - Zhang, Qiang

PY - 2020/1

Y1 - 2020/1

N2 - Solid-state lithium (Li) metal batteries, employing solid electrolytes, with high energy density and enhanced safety are promising choices for next-generation electrochemical energy storage devices. However, the large interfacial resistances seriously hinder their commercialization. To construct a conformal interface with acceptable resistances, introducing small amounts of additional liquid electrolytes is one of the most convenient and effective solutions. This review summarizes the fundamental understandings on the interfacial behaviors between liquid electrolytes, electrodes and solid-state electrolytes. Afterwards, emerging strategies are discussed, involving interfacial wetting, in situ polymerization and interfacial reactions. Finally, current limitations and perspectives are presented for liquid phase therapy regarding the interfacial science and engineering.

AB - Solid-state lithium (Li) metal batteries, employing solid electrolytes, with high energy density and enhanced safety are promising choices for next-generation electrochemical energy storage devices. However, the large interfacial resistances seriously hinder their commercialization. To construct a conformal interface with acceptable resistances, introducing small amounts of additional liquid electrolytes is one of the most convenient and effective solutions. This review summarizes the fundamental understandings on the interfacial behaviors between liquid electrolytes, electrodes and solid-state electrolytes. Afterwards, emerging strategies are discussed, involving interfacial wetting, in situ polymerization and interfacial reactions. Finally, current limitations and perspectives are presented for liquid phase therapy regarding the interfacial science and engineering.

KW - Electrolyte–electrode interface

KW - Liquid electrolyte

KW - Lithium metal anode

KW - Solid electrolyte interface

KW - Solid-state rechargeable batteries

UR - http://www.scopus.com/inward/record.url?scp=85069839604&partnerID=8YFLogxK

U2 - 10.1016/j.ensm.2019.07.026

DO - 10.1016/j.ensm.2019.07.026

M3 - Review article

AN - SCOPUS:85069839604

SN - 2405-8297

VL - 24

SP - 75

EP - 84

JO - Energy Storage Materials

JF - Energy Storage Materials

ER -

Liquid phase therapy to solid electrolyte–electrode interface in solid-state Li metal batteries: A review

Abstract

Keywords

UN SDGs

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