LiCu2[BP2O8(OH)2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

Miao Yang; Xinjie Li; Jihong Yu; Jingran Zhu; Xiaoxia Liu; Genfu Chen; Yan Yan

doi:10.1039/c3dt50591j

LiCu₂[BP₂O₈(OH)₂]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

Miao Yang^*, Xinjie Li, Jihong Yu, Jingran Zhu, Xiaoxia Liu, Genfu Chen, Yan Yan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A new chiral copper borophosphate, LiCu₂[BP₂O ₈(OH)₂] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.

Original language	English
Pages (from-to)	6298-6301
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	18
DOIs	https://doi.org/10.1039/c3dt50591j
Publication status	Published - 2013
Externally published	Yes

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Yang, M., Li, X., Yu, J., Zhu, J., Liu, X., Chen, G., & Yan, Y. (2013). LiCu₂[BP₂O₈(OH)₂]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization. Dalton Transactions, 42(18), 6298-6301. https://doi.org/10.1039/c3dt50591j

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abstract = "A new chiral copper borophosphate, LiCu2[BP2O 8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.",

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TY - JOUR

T1 - LiCu2[BP2O8(OH)2]

T2 - A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

AU - Yang, Miao

AU - Li, Xinjie

AU - Yu, Jihong

AU - Zhu, Jingran

AU - Liu, Xiaoxia

AU - Chen, Genfu

AU - Yan, Yan

PY - 2013

Y1 - 2013

N2 - A new chiral copper borophosphate, LiCu2[BP2O 8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.

AB - A new chiral copper borophosphate, LiCu2[BP2O 8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.

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U2 - 10.1039/c3dt50591j

DO - 10.1039/c3dt50591j

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IS - 18

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LiCu₂[BP₂O₈(OH)₂]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

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