Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth

Zishu Wang; Kai Qian; Murat Anil Öner; Peter S. Deimel; Yan Wang; Shuai Zhang; Xiaoxi Zhang; Vishal Gupta; Juan Li; Hong Jun Gao; David A. Duncan; Johannes V. Barth; Xiao Lin; Francesco Allegretti; Shixuan Du; Carlos Andres Palma

doi:10.1021/acsanm.0c02237

Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth

Zishu Wang, Kai Qian, Murat Anil Öner, Peter S. Deimel, Yan Wang, Shuai Zhang, Xiaoxi Zhang, Vishal Gupta, Juan Li, Hong Jun Gao, David A. Duncan, Johannes V. Barth, Xiao Lin, Francesco Allegretti^*, Shixuan Du, Carlos Andres Palma^*

^*Corresponding author for this work

Advanced Research Institute of Multidisciplinary Science

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Precisely layered molecular heterostructures are promising but still largely unexplored materials, with the potential to complement and enhance the scope of two-dimensional heterostructures. The controlled epitaxial growth of vertically stacked molecular layers connected through tailored linkers, can lead to significant development in the field. Here, we demonstrate that sequential assembly of prototypical iron porphyrins and axial ligands can be steered via temperature-programmed desorption, and monitored by mass spectrometry and by high-resolution atomic force microscopy under ultrahigh vacuum conditions. Complementary photoelectron spectroscopy analysis delivers chemical insight into the formation of layer-by-layer nanoarchitectures. Our temperature-directed methodology outlines a promising strategy for the in vacuo fabrication of precisely stacked, multicomponent (metal-organic) molecular heterostructures.

Original language	English
Pages (from-to)	11752-11759
Number of pages	8
Journal	ACS Applied Nano Materials
Volume	3
Issue number	12
DOIs	https://doi.org/10.1021/acsanm.0c02237
Publication status	Published - 24 Dec 2020

Keywords

bottom-up self-assembly
directed self-assembly
molecular architectures
photoemission
scanning probe microscopy
scanning tunneling microscopy
thermal desorption spectroscopy
three-dimensional atomically-precise fabrication

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10.1021/acsanm.0c02237

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Wang, Z., Qian, K., Öner, M. A., Deimel, P. S., Wang, Y., Zhang, S., Zhang, X., Gupta, V., Li, J., Gao, H. J., Duncan, D. A., Barth, J. V., Lin, X., Allegretti, F., Du, S., & Palma, C. A. (2020). Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth. ACS Applied Nano Materials, 3(12), 11752-11759. https://doi.org/10.1021/acsanm.0c02237

@article{72617182086b4100bcbadf5ee088883f,

title = "Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth",

abstract = "Precisely layered molecular heterostructures are promising but still largely unexplored materials, with the potential to complement and enhance the scope of two-dimensional heterostructures. The controlled epitaxial growth of vertically stacked molecular layers connected through tailored linkers, can lead to significant development in the field. Here, we demonstrate that sequential assembly of prototypical iron porphyrins and axial ligands can be steered via temperature-programmed desorption, and monitored by mass spectrometry and by high-resolution atomic force microscopy under ultrahigh vacuum conditions. Complementary photoelectron spectroscopy analysis delivers chemical insight into the formation of layer-by-layer nanoarchitectures. Our temperature-directed methodology outlines a promising strategy for the in vacuo fabrication of precisely stacked, multicomponent (metal-organic) molecular heterostructures.",

keywords = "bottom-up self-assembly, directed self-assembly, molecular architectures, photoemission, scanning probe microscopy, scanning tunneling microscopy, thermal desorption spectroscopy, three-dimensional atomically-precise fabrication",

author = "Zishu Wang and Kai Qian and {\"O}ner, {Murat Anil} and Deimel, {Peter S.} and Yan Wang and Shuai Zhang and Xiaoxi Zhang and Vishal Gupta and Juan Li and Gao, {Hong Jun} and Duncan, {David A.} and Barth, {Johannes V.} and Xiao Lin and Francesco Allegretti and Shixuan Du and Palma, {Carlos Andres}",

year = "2020",

month = dec,

day = "24",

doi = "10.1021/acsanm.0c02237",

language = "English",

volume = "3",

pages = "11752--11759",

journal = "ACS Applied Nano Materials",

issn = "2574-0970",

publisher = "American Chemical Society",

number = "12",

}

Wang, Z, Qian, K, Öner, MA, Deimel, PS, Wang, Y, Zhang, S, Zhang, X, Gupta, V, Li, J, Gao, HJ, Duncan, DA, Barth, JV, Lin, X, Allegretti, F, Du, S & Palma, CA 2020, 'Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth', ACS Applied Nano Materials, vol. 3, no. 12, pp. 11752-11759. https://doi.org/10.1021/acsanm.0c02237

TY - JOUR

T1 - Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth

AU - Wang, Zishu

AU - Qian, Kai

AU - Öner, Murat Anil

AU - Deimel, Peter S.

AU - Wang, Yan

AU - Zhang, Shuai

AU - Zhang, Xiaoxi

AU - Gupta, Vishal

AU - Li, Juan

AU - Gao, Hong Jun

AU - Duncan, David A.

AU - Barth, Johannes V.

AU - Lin, Xiao

AU - Allegretti, Francesco

AU - Du, Shixuan

AU - Palma, Carlos Andres

PY - 2020/12/24

Y1 - 2020/12/24

N2 - Precisely layered molecular heterostructures are promising but still largely unexplored materials, with the potential to complement and enhance the scope of two-dimensional heterostructures. The controlled epitaxial growth of vertically stacked molecular layers connected through tailored linkers, can lead to significant development in the field. Here, we demonstrate that sequential assembly of prototypical iron porphyrins and axial ligands can be steered via temperature-programmed desorption, and monitored by mass spectrometry and by high-resolution atomic force microscopy under ultrahigh vacuum conditions. Complementary photoelectron spectroscopy analysis delivers chemical insight into the formation of layer-by-layer nanoarchitectures. Our temperature-directed methodology outlines a promising strategy for the in vacuo fabrication of precisely stacked, multicomponent (metal-organic) molecular heterostructures.

AB - Precisely layered molecular heterostructures are promising but still largely unexplored materials, with the potential to complement and enhance the scope of two-dimensional heterostructures. The controlled epitaxial growth of vertically stacked molecular layers connected through tailored linkers, can lead to significant development in the field. Here, we demonstrate that sequential assembly of prototypical iron porphyrins and axial ligands can be steered via temperature-programmed desorption, and monitored by mass spectrometry and by high-resolution atomic force microscopy under ultrahigh vacuum conditions. Complementary photoelectron spectroscopy analysis delivers chemical insight into the formation of layer-by-layer nanoarchitectures. Our temperature-directed methodology outlines a promising strategy for the in vacuo fabrication of precisely stacked, multicomponent (metal-organic) molecular heterostructures.

KW - bottom-up self-assembly

KW - directed self-assembly

KW - molecular architectures

KW - photoemission

KW - scanning probe microscopy

KW - scanning tunneling microscopy

KW - thermal desorption spectroscopy

KW - three-dimensional atomically-precise fabrication

UR - http://www.scopus.com/inward/record.url?scp=85097950267&partnerID=8YFLogxK

U2 - 10.1021/acsanm.0c02237

DO - 10.1021/acsanm.0c02237

M3 - Article

AN - SCOPUS:85097950267

SN - 2574-0970

VL - 3

SP - 11752

EP - 11759

JO - ACS Applied Nano Materials

JF - ACS Applied Nano Materials

IS - 12

ER -

Layer-by-Layer Epitaxy of Porphyrin-Ligand Fe(II)-Fe(III) Nanoarchitectures for Advanced Metal-Organic Framework Growth

Abstract

Keywords

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