Sun, W. H., Jie, S., Zhang, S., Zhang, W., Song, Y., Ma, H., Chen, J., Wedeking, K., & Fröhlich, R. (2006). Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization. Organometallics, 25(3), 666-677. https://doi.org/10.1021/om050891p
Sun, Wen Hua ; Jie, Suyun ; Zhang, Shu et al. / Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization. In: Organometallics. 2006 ; Vol. 25, No. 3. pp. 666-677.
@article{c54e20003f2a437db8f7d0d7ccdf2d3c,
title = "Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization",
abstract = "A series of iron complexes ligated by 2-imino-1,10-phenanthrolinyl ligands, LFeCl2 (L = 2-(ArN=CR)-1,10-phen), were synthesized and sufficiently characterized by elemental and spectroscopic analysis along with X-ray diffraction analysis. Activated with methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), these iron(II) complexes show high catalytic activities up to 8.95 × 107 g mol-1(Fe) h -1 for ethylene oligomerization. The distribution of oligomers produced follows Schluz-Flory rules with high selectivity for α-olefins. Both the steric and electronic effects of coordinative ligands affect the catalytic activity and the properties of the catalytic products. The parameters of the reaction conditions were also investigated to explore the catalytic potentials of these complexes.",
author = "Sun, {Wen Hua} and Suyun Jie and Shu Zhang and Wen Zhang and Yingxia Song and Hongwei Ma and Jiutong Chen and Katrin Wedeking and Roland Fr{\"o}hlich",
year = "2006",
month = jan,
day = "30",
doi = "10.1021/om050891p",
language = "English",
volume = "25",
pages = "666--677",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "3",
}
Sun, WH, Jie, S, Zhang, S, Zhang, W, Song, Y, Ma, H, Chen, J, Wedeking, K & Fröhlich, R 2006, 'Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization', Organometallics, vol. 25, no. 3, pp. 666-677. https://doi.org/10.1021/om050891p
Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization. / Sun, Wen Hua; Jie, Suyun; Zhang, Shu et al.
In:
Organometallics, Vol. 25, No. 3, 30.01.2006, p. 666-677.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization
AU - Sun, Wen Hua
AU - Jie, Suyun
AU - Zhang, Shu
AU - Zhang, Wen
AU - Song, Yingxia
AU - Ma, Hongwei
AU - Chen, Jiutong
AU - Wedeking, Katrin
AU - Fröhlich, Roland
PY - 2006/1/30
Y1 - 2006/1/30
N2 - A series of iron complexes ligated by 2-imino-1,10-phenanthrolinyl ligands, LFeCl2 (L = 2-(ArN=CR)-1,10-phen), were synthesized and sufficiently characterized by elemental and spectroscopic analysis along with X-ray diffraction analysis. Activated with methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), these iron(II) complexes show high catalytic activities up to 8.95 × 107 g mol-1(Fe) h -1 for ethylene oligomerization. The distribution of oligomers produced follows Schluz-Flory rules with high selectivity for α-olefins. Both the steric and electronic effects of coordinative ligands affect the catalytic activity and the properties of the catalytic products. The parameters of the reaction conditions were also investigated to explore the catalytic potentials of these complexes.
AB - A series of iron complexes ligated by 2-imino-1,10-phenanthrolinyl ligands, LFeCl2 (L = 2-(ArN=CR)-1,10-phen), were synthesized and sufficiently characterized by elemental and spectroscopic analysis along with X-ray diffraction analysis. Activated with methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), these iron(II) complexes show high catalytic activities up to 8.95 × 107 g mol-1(Fe) h -1 for ethylene oligomerization. The distribution of oligomers produced follows Schluz-Flory rules with high selectivity for α-olefins. Both the steric and electronic effects of coordinative ligands affect the catalytic activity and the properties of the catalytic products. The parameters of the reaction conditions were also investigated to explore the catalytic potentials of these complexes.
UR - http://www.scopus.com/inward/record.url?scp=33644519296&partnerID=8YFLogxK
U2 - 10.1021/om050891p
DO - 10.1021/om050891p
M3 - Article
AN - SCOPUS:33644519296
SN - 0276-7333
VL - 25
SP - 666
EP - 677
JO - Organometallics
JF - Organometallics
IS - 3
ER -
Sun WH, Jie S, Zhang S, Zhang W, Song Y, Ma H et al. Iron complexes bearing 2-imino-1,10-phenanthrolinyl ligands as highly active catalysts for ethylene oligomerization. Organometallics. 2006 Jan 30;25(3):666-677. doi: 10.1021/om050891p
