Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA

Yu Chen; Huilu Chen; Yunfei Liu; Wei Yang; Hou Chen; Weishang Yao; Yili Wang; Xue Zhang

doi:10.1080/1023666X.2015.1018036

Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA

Yu Chen^*, Huilu Chen, Yunfei Liu, Wei Yang, Hou Chen, Weishang Yao, Yili Wang, Xue Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The copolymerization activity and sequence structure of the typical neutral polymer bonding agent (NPBA) for improving the mechanical properties of a composite solid propellant plasticized by nitrate ester were investigated. The reactivity ratios of three monomers were calculated and compared. In addition, by using Monte Carlo simulation, the effects of the monomers’ feed amount on composition and sequence structure of the copolymer were also investigated and discussed. The prepared NPBA bonding agents were used in a propellant. It was found that the results of the mechanical properties tests have good correspondence with the data of reactivity ratios and Monte Carlo simulation.

Original language	English
Pages (from-to)	344-356
Number of pages	13
Journal	International Journal of Polymer Analysis and Characterization
Volume	20
Issue number	4
DOIs	https://doi.org/10.1080/1023666X.2015.1018036
Publication status	Published - 19 May 2015

Keywords

Monte Carlo
Neutral polymer bonding agent
Reactivity ratio
Sequence structure
Structural controllability

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Chen, Y., Chen, H., Liu, Y., Yang, W., Chen, H., Yao, W., Wang, Y., & Zhang, X. (2015). Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA. International Journal of Polymer Analysis and Characterization, 20(4), 344-356. https://doi.org/10.1080/1023666X.2015.1018036

Chen, Yu ; Chen, Huilu ; Liu, Yunfei et al. / Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I : Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA. In: International Journal of Polymer Analysis and Characterization. 2015 ; Vol. 20, No. 4. pp. 344-356.

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title = "Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA",

abstract = "The copolymerization activity and sequence structure of the typical neutral polymer bonding agent (NPBA) for improving the mechanical properties of a composite solid propellant plasticized by nitrate ester were investigated. The reactivity ratios of three monomers were calculated and compared. In addition, by using Monte Carlo simulation, the effects of the monomers{\textquoteright} feed amount on composition and sequence structure of the copolymer were also investigated and discussed. The prepared NPBA bonding agents were used in a propellant. It was found that the results of the mechanical properties tests have good correspondence with the data of reactivity ratios and Monte Carlo simulation.",

keywords = "Monte Carlo, Neutral polymer bonding agent, Reactivity ratio, Sequence structure, Structural controllability",

author = "Yu Chen and Huilu Chen and Yunfei Liu and Wei Yang and Hou Chen and Weishang Yao and Yili Wang and Xue Zhang",

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year = "2015",

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Chen, Y, Chen, H, Liu, Y, Yang, W, Chen, H, Yao, W, Wang, Y & Zhang, X 2015, 'Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA', International Journal of Polymer Analysis and Characterization, vol. 20, no. 4, pp. 344-356. https://doi.org/10.1080/1023666X.2015.1018036

Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA. / Chen, Yu; Chen, Huilu; Liu, Yunfei et al.
In: International Journal of Polymer Analysis and Characterization, Vol. 20, No. 4, 19.05.2015, p. 344-356.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I

T2 - Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA

AU - Chen, Yu

AU - Chen, Huilu

AU - Liu, Yunfei

AU - Yang, Wei

AU - Chen, Hou

AU - Yao, Weishang

AU - Wang, Yili

AU - Zhang, Xue

PY - 2015/5/19

Y1 - 2015/5/19

N2 - The copolymerization activity and sequence structure of the typical neutral polymer bonding agent (NPBA) for improving the mechanical properties of a composite solid propellant plasticized by nitrate ester were investigated. The reactivity ratios of three monomers were calculated and compared. In addition, by using Monte Carlo simulation, the effects of the monomers’ feed amount on composition and sequence structure of the copolymer were also investigated and discussed. The prepared NPBA bonding agents were used in a propellant. It was found that the results of the mechanical properties tests have good correspondence with the data of reactivity ratios and Monte Carlo simulation.

AB - The copolymerization activity and sequence structure of the typical neutral polymer bonding agent (NPBA) for improving the mechanical properties of a composite solid propellant plasticized by nitrate ester were investigated. The reactivity ratios of three monomers were calculated and compared. In addition, by using Monte Carlo simulation, the effects of the monomers’ feed amount on composition and sequence structure of the copolymer were also investigated and discussed. The prepared NPBA bonding agents were used in a propellant. It was found that the results of the mechanical properties tests have good correspondence with the data of reactivity ratios and Monte Carlo simulation.

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Chen Y, Chen H, Liu Y, Yang W, Chen H, Yao W et al. Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA. International Journal of Polymer Analysis and Characterization. 2015 May 19;20(4):344-356. doi: 10.1080/1023666X.2015.1018036

Investigations on the Structure and Properties of Neutral Polymer Bonding Agents (NPBA) Used for Composite Solid Propellant. I: Study of the Reactivity Ratios and Sequence Structure Control of Acrylonitrile (AN)/Methacrylate (MA)/Hydroxyethyl Acrylate (HEA) Terpolymer Type NPBA

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Keywords

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