Abstract
Magnesium-doped boron nanoswords were synthesized via a thermoreduction method. The as-prepared nanoswords are single crystalline and -rhombohedral (-rh) phase. Electrical transport measurements show that variable range hopping conductivity increases with temperature, and carrier mobility has a greater influence than carrier concentration. These results are consistent with the three dimensional Mott's model (M. Cutler and N. F. Mott, Phys. Rev. 181, 1336 (1969)) besides a high density of localized states at the Fermi level compared with bulk -rh boron. Conductivity of Mg-doped boron nanoswords is significantly lower than that of pure (free of magnesium) boron nanoswords. Electron energy loss spectroscopy studies confirm that the poorer conductivity arises from silicon against magnesium doping.
Original language | English |
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Article number | 103112 |
Journal | Applied Physics Letters |
Volume | 100 |
Issue number | 10 |
DOIs | |
Publication status | Published - 5 Mar 2012 |
Externally published | Yes |