Influence of Si Co-doping on electrical transport properties of magnesium-doped boron nanoswords

Yuan Tian, Hongliang Lu, Jifa Tian, Chen Li, Chao Hui, Xuezhao Shi, Yuan Huang, Chengmin Shen, Hong Jun Gao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Magnesium-doped boron nanoswords were synthesized via a thermoreduction method. The as-prepared nanoswords are single crystalline and -rhombohedral (-rh) phase. Electrical transport measurements show that variable range hopping conductivity increases with temperature, and carrier mobility has a greater influence than carrier concentration. These results are consistent with the three dimensional Mott's model (M. Cutler and N. F. Mott, Phys. Rev. 181, 1336 (1969)) besides a high density of localized states at the Fermi level compared with bulk -rh boron. Conductivity of Mg-doped boron nanoswords is significantly lower than that of pure (free of magnesium) boron nanoswords. Electron energy loss spectroscopy studies confirm that the poorer conductivity arises from silicon against magnesium doping.

Original languageEnglish
Article number103112
JournalApplied Physics Letters
Volume100
Issue number10
DOIs
Publication statusPublished - 5 Mar 2012
Externally publishedYes

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