Influence of porous copper dimension on its azide reaction

Bing Li; Qing Xuan Zeng; Ming Yu Li; Xing Yu Wu

doi:10.11943/j.issn.1006-9941.2016.10.013

Influence of porous copper dimension on its azide reaction

Bing Li, Qing Xuan Zeng^*, Ming Yu Li, Xing Yu Wu

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

To study the influence of porous copper dimension on its azide reaction, according to the different solubleness of copper azides and copper at 50 ℃ in 0.5 mol·L^-1 diluted hydrochloric acid, the reaction characteristics of copper particles with different sizes and monolithic porous copper with particle size of about 200 nm, thickness of 0.2-0.3 mm and density of 1.51 g·cm^-3 with gaseous diazoimide were analyzed by an ICP spectrometer. Results show that when the size of copper particle is about 0.5 μm, the average conversion of copper particle can reach 95.64%, the copper particle can react with gaseous diazoimide completely. When the thickness of porous copper is 0.2 mm, the conversion of the azide is greater than 97%.

Original language	English
Pages (from-to)	995-999
Number of pages	5
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	24
Issue number	10
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2016.10.013
Publication status	Published - 25 Oct 2016

Keywords

Conversion
Copper particles
Gaseous diazoimide
Monolithic porous copper

Access to Document

10.11943/j.issn.1006-9941.2016.10.013

Cite this

@article{68a316d2909c445da5c59dc95369c6a1,

title = "Influence of porous copper dimension on its azide reaction",

abstract = "To study the influence of porous copper dimension on its azide reaction, according to the different solubleness of copper azides and copper at 50 ℃ in 0.5 mol·L-1 diluted hydrochloric acid, the reaction characteristics of copper particles with different sizes and monolithic porous copper with particle size of about 200 nm, thickness of 0.2-0.3 mm and density of 1.51 g·cm-3 with gaseous diazoimide were analyzed by an ICP spectrometer. Results show that when the size of copper particle is about 0.5 μm, the average conversion of copper particle can reach 95.64%, the copper particle can react with gaseous diazoimide completely. When the thickness of porous copper is 0.2 mm, the conversion of the azide is greater than 97%.",

keywords = "Conversion, Copper particles, Gaseous diazoimide, Monolithic porous copper",

author = "Bing Li and Zeng, {Qing Xuan} and Li, {Ming Yu} and Wu, {Xing Yu}",

year = "2016",

month = oct,

day = "25",

doi = "10.11943/j.issn.1006-9941.2016.10.013",

language = "English",

volume = "24",

pages = "995--999",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "10",

}

TY - JOUR

T1 - Influence of porous copper dimension on its azide reaction

AU - Li, Bing

AU - Zeng, Qing Xuan

AU - Li, Ming Yu

AU - Wu, Xing Yu

PY - 2016/10/25

Y1 - 2016/10/25

N2 - To study the influence of porous copper dimension on its azide reaction, according to the different solubleness of copper azides and copper at 50 ℃ in 0.5 mol·L-1 diluted hydrochloric acid, the reaction characteristics of copper particles with different sizes and monolithic porous copper with particle size of about 200 nm, thickness of 0.2-0.3 mm and density of 1.51 g·cm-3 with gaseous diazoimide were analyzed by an ICP spectrometer. Results show that when the size of copper particle is about 0.5 μm, the average conversion of copper particle can reach 95.64%, the copper particle can react with gaseous diazoimide completely. When the thickness of porous copper is 0.2 mm, the conversion of the azide is greater than 97%.

AB - To study the influence of porous copper dimension on its azide reaction, according to the different solubleness of copper azides and copper at 50 ℃ in 0.5 mol·L-1 diluted hydrochloric acid, the reaction characteristics of copper particles with different sizes and monolithic porous copper with particle size of about 200 nm, thickness of 0.2-0.3 mm and density of 1.51 g·cm-3 with gaseous diazoimide were analyzed by an ICP spectrometer. Results show that when the size of copper particle is about 0.5 μm, the average conversion of copper particle can reach 95.64%, the copper particle can react with gaseous diazoimide completely. When the thickness of porous copper is 0.2 mm, the conversion of the azide is greater than 97%.

KW - Conversion

KW - Copper particles

KW - Gaseous diazoimide

KW - Monolithic porous copper

UR - http://www.scopus.com/inward/record.url?scp=84991709734&partnerID=8YFLogxK

U2 - 10.11943/j.issn.1006-9941.2016.10.013

DO - 10.11943/j.issn.1006-9941.2016.10.013

M3 - Article

AN - SCOPUS:84991709734

SN - 1006-9941

VL - 24

SP - 995

EP - 999

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 10

ER -

Influence of porous copper dimension on its azide reaction

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this