Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

Mingyan Wu; Daqiang Yuan; Lei Han; Benlai Wu; Yanqing Xu; Maochun Hong

doi:10.1002/ejic.200500863

Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

Mingyan Wu, Daqiang Yuan, Lei Han, Benlai Wu, Yanqing Xu, Maochun Hong^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Reactions of the p-sulfonatothiacalix[4]arene salt (Na₄H ₄TCAS) and MSO₄ (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H ₂O)₄]²⁺C[Co₄(TCAS)(μ₄- SO₄)(H₂O)₄]^2-· 10.75H ₂O}_n (1) and ([Cu(2,2′-bpz)(H₂O) ₃]²⁺C[Cu₄(TCAS)(μ₄-SO ₄)(H₂O)₄]^2-·16H ₂O}_n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

Original language	English
Pages (from-to)	526-530
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	3
DOIs	https://doi.org/10.1002/ejic.200500863
Publication status	Published - 6 Feb 2006
Externally published	Yes

Keywords

Coordination polymer
Inclusion
Supramolecular chemistry
p-Sulfonatothiacalix[4]arene

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10.1002/ejic.200500863

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Wu, M., Yuan, D., Han, L., Wu, B., Xu, Y., & Hong, M. (2006). Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters. European Journal of Inorganic Chemistry, (3), 526-530. https://doi.org/10.1002/ejic.200500863

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title = "Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters",

abstract = "Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.",

keywords = "Coordination polymer, Inclusion, Supramolecular chemistry, p-Sulfonatothiacalix[4]arene",

author = "Mingyan Wu and Daqiang Yuan and Lei Han and Benlai Wu and Yanqing Xu and Maochun Hong",

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AU - Wu, Mingyan

AU - Yuan, Daqiang

AU - Han, Lei

AU - Wu, Benlai

AU - Xu, Yanqing

AU - Hong, Maochun

PY - 2006/2/6

Y1 - 2006/2/6

N2 - Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

AB - Reactions of the p-sulfonatothiacalix[4]arene salt (Na4H 4TCAS) and MSO4 (M = Co, Cu) in the presence of 2,2′-bipyrazine (2,2′-bpz) generated 2D coordination networks formed by tetranuclear cluster subunits, namely {[Co(2,2′-bpz)(H 2O)4]2+C[Co4(TCAS)(μ4- SO4)(H2O)4]2-· 10.75H 2O}n (1) and ([Cu(2,2′-bpz)(H2O) 3]2+C[Cu4(TCAS)(μ4-SO 4)(H2O)4]2-·16H 2O}n (2). X-ray diffraction analyses reveal that both these complexes include metal-2,2′-bipyrazine complexes into the hydrophobic cavities of p-sulfonatothiacalix[4]arenes as guests through supramolecular interactions.

KW - Coordination polymer

KW - Inclusion

KW - Supramolecular chemistry

KW - p-Sulfonatothiacalix[4]arene

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DO - 10.1002/ejic.200500863

M3 - Article

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SN - 1434-1948

SP - 526

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 3

ER -

Inclusion of metal complexes into cavities of 2D coordination networks built from p-sulfonatothiacalix[4]arene tetranuclear clusters

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Keywords

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