In situ synthesis of an inorganic-organic hybrid based on a molybdenum-oxo chain: [Cu 2(pz)(Mo 3O 10)] n

Xin Fang Wang; Xiao Yu Ma; Yan Qing Xu; Chang Wen Hu

doi:10.1080/00958972.2012.666533

In situ synthesis of an inorganic-organic hybrid based on a molybdenum-oxo chain: [Cu ₂(pz)(Mo ₃O ₁₀)] _n

Xin Fang Wang, Xiao Yu Ma, Yan Qing Xu^*, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A polyoxomolybdate, [Cu ₂(pz)(Mo ₃O ₁₀)] _n (pz=pyrazine) (1), has been synthesized hydrothermally and characterized by elemental analysis, IR, X-ray photoelectron spectra, and thermogravimetric analysis. Single-crystal X-ray diffraction demonstrates that 1 has a 3-D architecture constructed by combination of {Mo ₃O ₁₀} units and [Cu ₂(pz)] ²⁺. All the terminal oxygen atoms of the polyoxomolybdate are coordinated by univalent copper. Pyrazine came from in situ decarboxylation of 2-pyrazinecarboxylic acid and Cu ⁺ from the in situ reduction of Cu ²⁺ during the hydrothermal synthesis.

Original language	English
Pages (from-to)	1043-1050
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	65
Issue number	6
DOIs	https://doi.org/10.1080/00958972.2012.666533
Publication status	Published - 20 Mar 2012

Keywords

Decarboxylation
Deoxidization
In situ reaction
Polyoxomolybdate

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10.1080/00958972.2012.666533

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title = "In situ synthesis of an inorganic-organic hybrid based on a molybdenum-oxo chain: [Cu 2(pz)(Mo 3O 10)] n",

abstract = "A polyoxomolybdate, [Cu 2(pz)(Mo 3O 10)] n (pz=pyrazine) (1), has been synthesized hydrothermally and characterized by elemental analysis, IR, X-ray photoelectron spectra, and thermogravimetric analysis. Single-crystal X-ray diffraction demonstrates that 1 has a 3-D architecture constructed by combination of {Mo 3O 10} units and [Cu 2(pz)] 2+. All the terminal oxygen atoms of the polyoxomolybdate are coordinated by univalent copper. Pyrazine came from in situ decarboxylation of 2-pyrazinecarboxylic acid and Cu + from the in situ reduction of Cu 2+ during the hydrothermal synthesis.",

keywords = "Decarboxylation, Deoxidization, In situ reaction, Polyoxomolybdate",

author = "Wang, {Xin Fang} and Ma, {Xiao Yu} and Xu, {Yan Qing} and Hu, {Chang Wen}",

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T1 - In situ synthesis of an inorganic-organic hybrid based on a molybdenum-oxo chain

T2 - [Cu 2(pz)(Mo 3O 10)] n

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AU - Ma, Xiao Yu

AU - Xu, Yan Qing

AU - Hu, Chang Wen

PY - 2012/3/20

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N2 - A polyoxomolybdate, [Cu 2(pz)(Mo 3O 10)] n (pz=pyrazine) (1), has been synthesized hydrothermally and characterized by elemental analysis, IR, X-ray photoelectron spectra, and thermogravimetric analysis. Single-crystal X-ray diffraction demonstrates that 1 has a 3-D architecture constructed by combination of {Mo 3O 10} units and [Cu 2(pz)] 2+. All the terminal oxygen atoms of the polyoxomolybdate are coordinated by univalent copper. Pyrazine came from in situ decarboxylation of 2-pyrazinecarboxylic acid and Cu + from the in situ reduction of Cu 2+ during the hydrothermal synthesis.

AB - A polyoxomolybdate, [Cu 2(pz)(Mo 3O 10)] n (pz=pyrazine) (1), has been synthesized hydrothermally and characterized by elemental analysis, IR, X-ray photoelectron spectra, and thermogravimetric analysis. Single-crystal X-ray diffraction demonstrates that 1 has a 3-D architecture constructed by combination of {Mo 3O 10} units and [Cu 2(pz)] 2+. All the terminal oxygen atoms of the polyoxomolybdate are coordinated by univalent copper. Pyrazine came from in situ decarboxylation of 2-pyrazinecarboxylic acid and Cu + from the in situ reduction of Cu 2+ during the hydrothermal synthesis.

KW - Decarboxylation

KW - Deoxidization

KW - In situ reaction

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In situ synthesis of an inorganic-organic hybrid based on a molybdenum-oxo chain: [Cu ₂(pz)(Mo ₃O ₁₀)] _n

Abstract

Keywords

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