In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen

Ji Kun Li; Yan Qing Xu; Chang Wen Hu

doi:10.1016/j.inoche.2015.07.023

In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen

Ji Kun Li, Yan Qing Xu^*, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Abstract A novel dioxidovanadium-based nickel complex [Ni₂(C₂O₄)(dpa)₄][(C₄H₆O₄)(VO₂)]₂·2[CH₃OH] (dpa = 2,2'-dipyridine amine) was in situ synthesized by a facile procedure and further used as catalyst to oxidize sulfur-containing heterocyclic compounds to corresponding sulfones using molecular oxygen as the oxidant and isobutyl aldehyde as the sacrificial agent in model oil under mild conditions.

Original language	English
Article number	6061
Pages (from-to)	12-14
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	60
DOIs	https://doi.org/10.1016/j.inoche.2015.07.023
Publication status	Published - 4 Aug 2015

Keywords

Catalytic reaction
Dioxidovanadium-based complex
In situ synthesis
Oxidative desulfurization

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10.1016/j.inoche.2015.07.023

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title = "In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen",

abstract = "Abstract A novel dioxidovanadium-based nickel complex [Ni2(C2O4)(dpa)4][(C4H6O4)(VO2)]2·2[CH3OH] (dpa = 2,2'-dipyridine amine) was in situ synthesized by a facile procedure and further used as catalyst to oxidize sulfur-containing heterocyclic compounds to corresponding sulfones using molecular oxygen as the oxidant and isobutyl aldehyde as the sacrificial agent in model oil under mild conditions.",

keywords = "Catalytic reaction, Dioxidovanadium-based complex, In situ synthesis, Oxidative desulfurization",

author = "Li, {Ji Kun} and Xu, {Yan Qing} and Hu, {Chang Wen}",

note = "Publisher Copyright: {\textcopyright} 2015 Published by Elsevier B.V.",

year = "2015",

month = aug,

day = "4",

doi = "10.1016/j.inoche.2015.07.023",

language = "English",

volume = "60",

pages = "12--14",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen

AU - Li, Ji Kun

AU - Xu, Yan Qing

AU - Hu, Chang Wen

PY - 2015/8/4

Y1 - 2015/8/4

N2 - Abstract A novel dioxidovanadium-based nickel complex [Ni2(C2O4)(dpa)4][(C4H6O4)(VO2)]2·2[CH3OH] (dpa = 2,2'-dipyridine amine) was in situ synthesized by a facile procedure and further used as catalyst to oxidize sulfur-containing heterocyclic compounds to corresponding sulfones using molecular oxygen as the oxidant and isobutyl aldehyde as the sacrificial agent in model oil under mild conditions.

AB - Abstract A novel dioxidovanadium-based nickel complex [Ni2(C2O4)(dpa)4][(C4H6O4)(VO2)]2·2[CH3OH] (dpa = 2,2'-dipyridine amine) was in situ synthesized by a facile procedure and further used as catalyst to oxidize sulfur-containing heterocyclic compounds to corresponding sulfones using molecular oxygen as the oxidant and isobutyl aldehyde as the sacrificial agent in model oil under mild conditions.

KW - Catalytic reaction

KW - Dioxidovanadium-based complex

KW - In situ synthesis

KW - Oxidative desulfurization

UR - http://www.scopus.com/inward/record.url?scp=84938326545&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2015.07.023

DO - 10.1016/j.inoche.2015.07.023

M3 - Article

AN - SCOPUS:84938326545

SN - 1387-7003

VL - 60

SP - 12

EP - 14

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 6061

ER -

In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen

Abstract

Keywords

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