Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Guillermina L. Luque*, Yan Li, Xiaoqiao Zeng, Xiangyi Luo, Ezequiel P.M. Leiva, Zonghai Chen, Khalil Amine

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The electrochemical performance of SiO–SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH 3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Particularly, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.

Original languageEnglish
Pages (from-to)397-405
Number of pages9
JournalJournal of Solid State Electrochemistry
Volume23
Issue number2
DOIs
Publication statusPublished - 12 Feb 2019
Externally publishedYes

Keywords

  • Alginate
  • Anode
  • Fluoroethylene carbonate
  • Lithium-ion batteries
  • Parasitic reaction
  • Self-discharge

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