Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages

De Xin Hu; Pang kuan Chen; Feng Luo; Yun Xia Che; Ji Min Zheng

doi:10.1016/j.molstruc.2006.10.027

Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages

De Xin Hu, Pang kuan Chen, Feng Luo, Yun Xia Che, Ji Min Zheng^*

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n 1 and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n 2 (H₂isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P2₁/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ₂-Ocoo^- groups to form the [Ln2-(μ₂-Ocoo^-)₂-Ln1]_n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy³⁺ ions in compound 2.

Original language	English
Pages (from-to)	179-184
Number of pages	6
Journal	Journal of Molecular Structure
Volume	837
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2006.10.027
Publication status	Published - 30 Jun 2007
Externally published	Yes

Keywords

Antiferromagnetic
Hydrothermal reaction
Isophthalate
Lanthanide
Ligand

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10.1016/j.molstruc.2006.10.027

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Hu, D. X., Chen, P. K., Luo, F., Che, Y. X., & Zheng, J. M. (2007). Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages. Journal of Molecular Structure, 837(1-3), 179-184. https://doi.org/10.1016/j.molstruc.2006.10.027

@article{5a72bda9c1d8400080a807b3d1ad6d73,

title = "Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages",

abstract = "Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.",

keywords = "Antiferromagnetic, Hydrothermal reaction, Isophthalate, Lanthanide, Ligand",

author = "Hu, {De Xin} and Chen, {Pang kuan} and Feng Luo and Che, {Yun Xia} and Zheng, {Ji Min}",

year = "2007",

month = jun,

day = "30",

doi = "10.1016/j.molstruc.2006.10.027",

language = "English",

volume = "837",

pages = "179--184",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

Hu, DX, Chen, PK, Luo, F, Che, YX & Zheng, JM 2007, 'Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages', Journal of Molecular Structure, vol. 837, no. 1-3, pp. 179-184. https://doi.org/10.1016/j.molstruc.2006.10.027

Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La₂(isophth)₂(Hisophth)₂(H₂O) · H₂O]_n and [Dy₄(isophth)₄(Ac)₄(H₂O)₈ · 2H₂O]_n, possessing infinite Ln-O-Ln linkages. / Hu, De Xin; Chen, Pang kuan; Luo, Feng et al.
In: Journal of Molecular Structure, Vol. 837, No. 1-3, 30.06.2007, p. 179-184.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n, possessing infinite Ln-O-Ln linkages

AU - Hu, De Xin

AU - Chen, Pang kuan

AU - Luo, Feng

AU - Che, Yun Xia

AU - Zheng, Ji Min

PY - 2007/6/30

Y1 - 2007/6/30

N2 - Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.

AB - Two lanthanide benzenedicarboxylates, [La2(isophth)2(Hisophth)2(H2O) · H2O]n 1 and [Dy4(isophth)4(Ac)4(H2O)8 · 2H2O]n 2 (H2isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monoclinic system with P21/c space group. The X-ray single-crystal structure analysis reveals that center metal ions Ln(III) are nine-coordinated and linked by μ2-Ocoo- groups to form the [Ln2-(μ2-Ocoo-)2-Ln1]n inorganic-organic chains and finally to furnish the supramolecular framework structures. The thermogravimetric analyses were carried out to examine the thermal stability of these two complexes. Magnetic studies on the polycrystalline sample shows the existence of strong antiferromagnetic couplings between the adjacent Dy3+ ions in compound 2.

KW - Antiferromagnetic

KW - Hydrothermal reaction

KW - Isophthalate

KW - Lanthanide

KW - Ligand

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U2 - 10.1016/j.molstruc.2006.10.027

DO - 10.1016/j.molstruc.2006.10.027

M3 - Article

AN - SCOPUS:34247127830

SN - 0022-2860

VL - 837

SP - 179

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JF - Journal of Molecular Structure

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