Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

H. Y. Bie; J. H. Yu; D. Q. Chu; J. Q. Xu; J. Lu; Y. H. Sun; X. B. Cui; Y. Li; X. Zhang

Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

H. Y. Bie, J. H. Yu, D. Q. Chu, J. Q. Xu^*, J. Lu, Y. H. Sun, X. B. Cui, Y. Li, X. Zhang

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Under hydrothermal conditions, reaction of Na₄[Fe(CN) ₆], NiCl₂ and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)₂][Fe(CN) ₄] 1. The structure consists of one octahedral [Ni(dien) ₂]²⁺ cation, square [Fe(CN)₄]^2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α₂ = 2.10×10^-11 m w^-1, n₂ = -2.05×10^-18 m² w^-1, respectively, and third-order NLO susceptibility χ⁽³⁾ 2.73×10^-10 esu.

Original language	English
Pages (from-to)	1969-1978
Number of pages	10
Journal	Polish Journal of Chemistry
Volume	78
Issue number	11-12
Publication status	Published - Nov 2004
Externally published	Yes

Keywords

Crystal structure
Cyanide complex
Hydrothermal reaction
Magnetic property
NLO property

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title = "Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound",

abstract = "Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.",

keywords = "Crystal structure, Cyanide complex, Hydrothermal reaction, Magnetic property, NLO property",

author = "Bie, {H. Y.} and Yu, {J. H.} and Chu, {D. Q.} and Xu, {J. Q.} and J. Lu and Sun, {Y. H.} and Cui, {X. B.} and Y. Li and X. Zhang",

year = "2004",

month = nov,

language = "English",

volume = "78",

pages = "1969--1978",

journal = "Polish Journal of Chemistry",

issn = "0137-5083",

publisher = "Polish Chemical Society",

number = "11-12",

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TY - JOUR

T1 - Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

AU - Bie, H. Y.

AU - Yu, J. H.

AU - Chu, D. Q.

AU - Xu, J. Q.

AU - Lu, J.

AU - Sun, Y. H.

AU - Cui, X. B.

AU - Li, Y.

AU - Zhang, X.

PY - 2004/11

Y1 - 2004/11

N2 - Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.

AB - Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.

KW - Crystal structure

KW - Cyanide complex

KW - Hydrothermal reaction

KW - Magnetic property

KW - NLO property

UR - http://www.scopus.com/inward/record.url?scp=10944244150&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:10944244150

SN - 0137-5083

VL - 78

SP - 1969

EP - 1978

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 11-12

ER -

Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

Abstract

Keywords

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