Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2]

Mei Wang; Ji Yang Li; Yi Li; Xiao Wei Song; Ji Hong Yu; Ru Ren Xu

Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C₄H₁₂N₂][Al₂ (PO₄)₂(H₂O)₂ F₂]

Mei Wang, Ji Yang Li^*, Yi Li, Xiao Wei Song, Ji Hong Yu, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new layered fluoroaluminophosphate [C₄H₁₂N₂][Al₂ (PO₄)₂(H₂O)₂ F₂] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P2₁/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R₁=0.0379, wR₂=0.0792 (all data). Its structure contains [Al₂(PO₄)₂ (H₂O)₂ F₂]^2- macroanonic sheets built up from PO₃(=O) tetrahedra and AlO₃F₂(H₂O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.

Original language	English
Pages (from-to)	1027-1029
Number of pages	3
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	26
Issue number	6
Publication status	Published - Jun 2005
Externally published	Yes

Keywords

Fluoroaluminophosphate
Host-guest interaction
Hydrothermal synthesis
Layered structure

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title = "Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2]",

abstract = "A new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P21/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R1=0.0379, wR2=0.0792 (all data). Its structure contains [Al2(PO4)2 (H2O)2 F2]2- macroanonic sheets built up from PO3(=O) tetrahedra and AlO3F2(H2O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.",

keywords = "Fluoroaluminophosphate, Host-guest interaction, Hydrothermal synthesis, Layered structure",

author = "Mei Wang and Li, {Ji Yang} and Yi Li and Song, {Xiao Wei} and Yu, {Ji Hong} and Xu, {Ru Ren}",

year = "2005",

month = jun,

language = "English",

volume = "26",

pages = "1027--1029",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "6",

}

TY - JOUR

T1 - Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2]

AU - Wang, Mei

AU - Li, Ji Yang

AU - Li, Yi

AU - Song, Xiao Wei

AU - Yu, Ji Hong

AU - Xu, Ru Ren

PY - 2005/6

Y1 - 2005/6

N2 - A new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P21/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R1=0.0379, wR2=0.0792 (all data). Its structure contains [Al2(PO4)2 (H2O)2 F2]2- macroanonic sheets built up from PO3(=O) tetrahedra and AlO3F2(H2O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.

AB - A new layered fluoroaluminophosphate [C4H12N2][Al2 (PO4)2(H2O)2 F2] (compound I) was synthesized hydrothermally. It crystallizes in the monoclinic space group P21/c with a=1.10240(7) nm, b=0.69551(4) nm, c=0.92805(5) nm, β=111.027(3)°, Z=6, R1=0.0379, wR2=0.0792 (all data). Its structure contains [Al2(PO4)2 (H2O)2 F2]2- macroanonic sheets built up from PO3(=O) tetrahedra and AlO3F2(H2O) octahedra to form three-, four-, six-membered ring-net stacked sheets in an AAAA sequence along [100] direction. The sheets are held together by diprotonated piperazine cations decomposed from 1-methylpiperazine through extensive hydrogen bonds.

KW - Fluoroaluminophosphate

KW - Host-guest interaction

KW - Hydrothermal synthesis

KW - Layered structure

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M3 - Article

AN - SCOPUS:21144438624

SN - 0251-0790

VL - 26

SP - 1027

EP - 1029

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 6

ER -

Hydrothermal synthesis and characterization of a new layered fluoroaluminophosphate [C₄H₁₂N₂][Al₂ (PO₄)₂(H₂O)₂ F₂]

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