Hydrogen-bonded helices in the layered aluminophosphate (C 2H8N)2[Al2(HPO4)(PO 42]

Yu Song; Jihong Yu; Yi Li; Guanghua Li; Ruren Xu

doi:10.1002/anie.200353118

Hydrogen-bonded helices in the layered aluminophosphate (C ₂H₈N)₂[Al₂(HPO₄)(PO ₄₂]

Yu Song, Jihong Yu^*, Yi Li, Guanghua Li, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Solvothermal combinatorial chemistry affords the layered aluminophosphate (C₂H₈N)₂[Al₂(HPO₄) (PO₄)₂]. The macroanionicc layer is based on alternating AlO₄ and PO₄ tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH₃)₂NH₂⁺ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.

Original language	English
Pages (from-to)	2399-2402
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	18
DOIs	https://doi.org/10.1002/anie.200353118
Publication status	Published - 26 Apr 2004
Externally published	Yes

Keywords

Aluminophosphates
Combinatorial chemistry
Hydrogen bonds
Layered compounds
Template synthesis

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10.1002/anie.200353118

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title = "Hydrogen-bonded helices in the layered aluminophosphate (C 2H8N)2[Al2(HPO4)(PO 42]",

abstract = "Solvothermal combinatorial chemistry affords the layered aluminophosphate (C2H8N)2[Al2(HPO4) (PO4)2]. The macroanionicc layer is based on alternating AlO4 and PO4 tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH3)2NH2+ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.",

keywords = "Aluminophosphates, Combinatorial chemistry, Hydrogen bonds, Layered compounds, Template synthesis",

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AU - Li, Yi

AU - Li, Guanghua

AU - Xu, Ruren

PY - 2004/4/26

Y1 - 2004/4/26

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AB - Solvothermal combinatorial chemistry affords the layered aluminophosphate (C2H8N)2[Al2(HPO4) (PO4)2]. The macroanionicc layer is based on alternating AlO4 and PO4 tetrahedra linked through vertex oxygen atoms to form 4.8-net sheets, stacked in an ABCD sequence along the c axis. The (CH3)2NH2+ ions between the inorganic layers interact with the terminal P=O groups to form left- and right-handed helices (see picture) along the b axis.

KW - Aluminophosphates

KW - Combinatorial chemistry

KW - Hydrogen bonds

KW - Layered compounds

KW - Template synthesis

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Hydrogen-bonded helices in the layered aluminophosphate (C ₂H₈N)₂[Al₂(HPO₄)(PO ₄₂]

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Keywords

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