Highly effective photoativation Pd catalyst for Suzuki coupling reaction

Dan Liu; Yinchao Yao; Zhiyi Sun; Zhonghua Xia; Zhuo Chen

doi:10.1016/j.mcat.2023.113659

Highly effective photoativation Pd catalyst for Suzuki coupling reaction

Dan Liu, Yinchao Yao, Zhiyi Sun, Zhonghua Xia, Zhuo Chen^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Suzuki coupling reaction is widely applied for constructing biaryl skeletons in various fields. Designing and developing highly effective catalysts are essential regarding the Suzuki coupling reaction. Here, we report a simple light irradiation approach to achieve the highly efficient Suzuki coupling reaction via the application of low valence Pd homogeneous catalyst. The catalyst exhibited a TOF value of 76,000 h⁻¹. We systematically investigated the impact of various experimental conditions on catalytic performance and further clarify the evolution of Pd species during the light irradiation and catalytic reaction process. This work provides a facile strategy for designing highly effective catalysts for the Suzuki coupling reaction and understanding the detailed evolution process of Pd during the reaction process.

Original language	English
Article number	113659
Journal	Molecular Catalysis
Volume	551
DOIs	https://doi.org/10.1016/j.mcat.2023.113659
Publication status	Published - Dec 2023

Keywords

Pd homogeneous catalyst
Photo activation
Suzuki coupling

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10.1016/j.mcat.2023.113659

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title = "Highly effective photoativation Pd catalyst for Suzuki coupling reaction",

abstract = "Suzuki coupling reaction is widely applied for constructing biaryl skeletons in various fields. Designing and developing highly effective catalysts are essential regarding the Suzuki coupling reaction. Here, we report a simple light irradiation approach to achieve the highly efficient Suzuki coupling reaction via the application of low valence Pd homogeneous catalyst. The catalyst exhibited a TOF value of 76,000 h−1. We systematically investigated the impact of various experimental conditions on catalytic performance and further clarify the evolution of Pd species during the light irradiation and catalytic reaction process. This work provides a facile strategy for designing highly effective catalysts for the Suzuki coupling reaction and understanding the detailed evolution process of Pd during the reaction process.",

keywords = "Pd homogeneous catalyst, Photo activation, Suzuki coupling",

author = "Dan Liu and Yinchao Yao and Zhiyi Sun and Zhonghua Xia and Zhuo Chen",

note = "Publisher Copyright: {\textcopyright} 2023",

year = "2023",

month = dec,

doi = "10.1016/j.mcat.2023.113659",

language = "English",

volume = "551",

journal = "Molecular Catalysis",

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T1 - Highly effective photoativation Pd catalyst for Suzuki coupling reaction

AU - Liu, Dan

AU - Yao, Yinchao

AU - Sun, Zhiyi

AU - Xia, Zhonghua

AU - Chen, Zhuo

PY - 2023/12

Y1 - 2023/12

N2 - Suzuki coupling reaction is widely applied for constructing biaryl skeletons in various fields. Designing and developing highly effective catalysts are essential regarding the Suzuki coupling reaction. Here, we report a simple light irradiation approach to achieve the highly efficient Suzuki coupling reaction via the application of low valence Pd homogeneous catalyst. The catalyst exhibited a TOF value of 76,000 h−1. We systematically investigated the impact of various experimental conditions on catalytic performance and further clarify the evolution of Pd species during the light irradiation and catalytic reaction process. This work provides a facile strategy for designing highly effective catalysts for the Suzuki coupling reaction and understanding the detailed evolution process of Pd during the reaction process.

AB - Suzuki coupling reaction is widely applied for constructing biaryl skeletons in various fields. Designing and developing highly effective catalysts are essential regarding the Suzuki coupling reaction. Here, we report a simple light irradiation approach to achieve the highly efficient Suzuki coupling reaction via the application of low valence Pd homogeneous catalyst. The catalyst exhibited a TOF value of 76,000 h−1. We systematically investigated the impact of various experimental conditions on catalytic performance and further clarify the evolution of Pd species during the light irradiation and catalytic reaction process. This work provides a facile strategy for designing highly effective catalysts for the Suzuki coupling reaction and understanding the detailed evolution process of Pd during the reaction process.

KW - Pd homogeneous catalyst

KW - Photo activation

KW - Suzuki coupling

UR - http://www.scopus.com/inward/record.url?scp=85175165575&partnerID=8YFLogxK

U2 - 10.1016/j.mcat.2023.113659

DO - 10.1016/j.mcat.2023.113659

M3 - Article

AN - SCOPUS:85175165575

SN - 2468-8231

VL - 551

JO - Molecular Catalysis

JF - Molecular Catalysis

M1 - 113659

ER -

Highly effective photoativation Pd catalyst for Suzuki coupling reaction

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Keywords

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