Hexaaquamanganese(II) bis[5-(4-cyanophenyl)-2H-tetrazolate]

Zhijie Ma; Jun Tao; Rong Bin Huang; Lan Sun Zhang

doi:10.1107/S160053680403106X

Hexaaquamanganese(II) bis[5-(4-cyanophenyl)-2H-tetrazolate]

Zhijie Ma, Jun Tao, Rong Bin Huang^*, Lan Sun Zhang

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The reaction of terephthalonitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The Mn^II atom in the title compound, [Mn(H₂O)₆](C₈H₄N₅) ₂, is coordinated by six water molecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.

Original language	English
Pages (from-to)	m1-m2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	1
DOIs	https://doi.org/10.1107/S160053680403106X
Publication status	Published - Jan 2005
Externally published	Yes

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Ma, Z., Tao, J., Huang, R. B., & Zhang, L. S. (2005). Hexaaquamanganese(II) bis[5-(4-cyanophenyl)-2H-tetrazolate]. Acta Crystallographica Section E: Structure Reports Online, 61(1), m1-m2. https://doi.org/10.1107/S160053680403106X

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abstract = "The reaction of terephthalonitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The MnII atom in the title compound, [Mn(H2O)6](C8H4N5) 2, is coordinated by six water molecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.",

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T1 - Hexaaquamanganese(II) bis[5-(4-cyanophenyl)-2H-tetrazolate]

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AU - Tao, Jun

AU - Huang, Rong Bin

AU - Zhang, Lan Sun

PY - 2005/1

Y1 - 2005/1

N2 - The reaction of terephthalonitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The MnII atom in the title compound, [Mn(H2O)6](C8H4N5) 2, is coordinated by six water molecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.

AB - The reaction of terephthalonitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The MnII atom in the title compound, [Mn(H2O)6](C8H4N5) 2, is coordinated by six water molecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.

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ER -

Hexaaquamanganese(II) bis[5-(4-cyanophenyl)-2H-tetrazolate]

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