Fused heterocycle-based energetic salts: Alliance of pyrazole and 1,2,3-triazole

Ping Yin, Chunlin He, Jean'ne M. Shreeve*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

90 Citations (Scopus)

Abstract

Energetic salts based on the 6-nitropyrazolo[3,4-d][1,2,3]triazol-3(4H)-olate anion were synthesized via a cyclization reaction of N-methyl or N,N′-ethylene substituted 4-chloro-3,5-dinitro pyrazole and hydrazine hydrate. All energetic salts were well characterized by differential scanning calorimetry (DSC), elemental analyses, and IR and multinuclear NMR spectroscopy. Energetic properties, including density, detonation velocity and detonation pressure, were evaluated for these nitrogen-rich fused heterocycles as a family of new energetic materials.

Original languageEnglish
Pages (from-to)1514-1519
Number of pages6
JournalJournal of Materials Chemistry A
Volume4
Issue number4
DOIs
Publication statusPublished - 28 Jan 2016
Externally publishedYes

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