TY - JOUR
T1 - Fused heterocycle-based energetic salts
T2 - Alliance of pyrazole and 1,2,3-triazole
AU - Yin, Ping
AU - He, Chunlin
AU - Shreeve, Jean'ne M.
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2016.
PY - 2016/1/28
Y1 - 2016/1/28
N2 - Energetic salts based on the 6-nitropyrazolo[3,4-d][1,2,3]triazol-3(4H)-olate anion were synthesized via a cyclization reaction of N-methyl or N,N′-ethylene substituted 4-chloro-3,5-dinitro pyrazole and hydrazine hydrate. All energetic salts were well characterized by differential scanning calorimetry (DSC), elemental analyses, and IR and multinuclear NMR spectroscopy. Energetic properties, including density, detonation velocity and detonation pressure, were evaluated for these nitrogen-rich fused heterocycles as a family of new energetic materials.
AB - Energetic salts based on the 6-nitropyrazolo[3,4-d][1,2,3]triazol-3(4H)-olate anion were synthesized via a cyclization reaction of N-methyl or N,N′-ethylene substituted 4-chloro-3,5-dinitro pyrazole and hydrazine hydrate. All energetic salts were well characterized by differential scanning calorimetry (DSC), elemental analyses, and IR and multinuclear NMR spectroscopy. Energetic properties, including density, detonation velocity and detonation pressure, were evaluated for these nitrogen-rich fused heterocycles as a family of new energetic materials.
UR - http://www.scopus.com/inward/record.url?scp=84955251186&partnerID=8YFLogxK
U2 - 10.1039/c5ta09999d
DO - 10.1039/c5ta09999d
M3 - Article
AN - SCOPUS:84955251186
SN - 2050-7488
VL - 4
SP - 1514
EP - 1519
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 4
ER -