Functionalization of disubstituted polyacetylenes through polymer reactions: Syntheses of functional poly(1-phenyl-1-alkyne)s

Zhen Li; Yongqiang Dong; Anjun Qin; Jacky W.Y. Lam; Yuping Dong; Wangzhang Yuan; Jingzhi Sun; Jianli Hua; Kam Sing Wong; Ben Zhong Tang

doi:10.1021/ma051907q

Functionalization of disubstituted polyacetylenes through polymer reactions: Syntheses of functional poly(1-phenyl-1-alkyne)s

Zhen Li, Yongqiang Dong, Anjun Qin, Jacky W.Y. Lam, Yuping Dong, Wangzhang Yuan, Jingzhi Sun, Jianli Hua, Kam Sing Wong, Ben Zhong Tang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

A polymer reaction route for molecular functionalization of distributed polyacetylenes containing reactive diarylethylene and polar pryridyl and amido units was investigated. The synthetic route was prepared by directly polymerizing its monomers and then subjecting the polymer intermediate to the reactions with desired functional groups. The reaction products were characterized by spectroscopic analysis, with all the polymers providing data corresponding to their expected molecular structure. It was found that the acetylenic triple bonds embedded in the scaffolds of the polymers enable them to be thermally cured, photonically cross-linked, and coordinatively metallized.

Original language	English
Pages (from-to)	467-469
Number of pages	3
Journal	Macromolecules
Volume	39
Issue number	2
DOIs	https://doi.org/10.1021/ma051907q
Publication status	Published - 24 Jan 2006
Externally published	Yes

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title = "Functionalization of disubstituted polyacetylenes through polymer reactions: Syntheses of functional poly(1-phenyl-1-alkyne)s",

abstract = "A polymer reaction route for molecular functionalization of distributed polyacetylenes containing reactive diarylethylene and polar pryridyl and amido units was investigated. The synthetic route was prepared by directly polymerizing its monomers and then subjecting the polymer intermediate to the reactions with desired functional groups. The reaction products were characterized by spectroscopic analysis, with all the polymers providing data corresponding to their expected molecular structure. It was found that the acetylenic triple bonds embedded in the scaffolds of the polymers enable them to be thermally cured, photonically cross-linked, and coordinatively metallized.",

author = "Zhen Li and Yongqiang Dong and Anjun Qin and Lam, {Jacky W.Y.} and Yuping Dong and Wangzhang Yuan and Jingzhi Sun and Jianli Hua and Wong, {Kam Sing} and Tang, {Ben Zhong}",

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doi = "10.1021/ma051907q",

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T1 - Functionalization of disubstituted polyacetylenes through polymer reactions

T2 - Syntheses of functional poly(1-phenyl-1-alkyne)s

AU - Li, Zhen

AU - Dong, Yongqiang

AU - Qin, Anjun

AU - Lam, Jacky W.Y.

AU - Dong, Yuping

AU - Yuan, Wangzhang

AU - Sun, Jingzhi

AU - Hua, Jianli

AU - Wong, Kam Sing

AU - Tang, Ben Zhong

PY - 2006/1/24

Y1 - 2006/1/24

N2 - A polymer reaction route for molecular functionalization of distributed polyacetylenes containing reactive diarylethylene and polar pryridyl and amido units was investigated. The synthetic route was prepared by directly polymerizing its monomers and then subjecting the polymer intermediate to the reactions with desired functional groups. The reaction products were characterized by spectroscopic analysis, with all the polymers providing data corresponding to their expected molecular structure. It was found that the acetylenic triple bonds embedded in the scaffolds of the polymers enable them to be thermally cured, photonically cross-linked, and coordinatively metallized.

AB - A polymer reaction route for molecular functionalization of distributed polyacetylenes containing reactive diarylethylene and polar pryridyl and amido units was investigated. The synthetic route was prepared by directly polymerizing its monomers and then subjecting the polymer intermediate to the reactions with desired functional groups. The reaction products were characterized by spectroscopic analysis, with all the polymers providing data corresponding to their expected molecular structure. It was found that the acetylenic triple bonds embedded in the scaffolds of the polymers enable them to be thermally cured, photonically cross-linked, and coordinatively metallized.

UR - http://www.scopus.com/inward/record.url?scp=31544453334&partnerID=8YFLogxK

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DO - 10.1021/ma051907q

M3 - Article

AN - SCOPUS:31544453334

SN - 0024-9297

VL - 39

SP - 467

EP - 469

JO - Macromolecules

JF - Macromolecules

IS - 2

ER -

Functionalization of disubstituted polyacetylenes through polymer reactions: Syntheses of functional poly(1-phenyl-1-alkyne)s

Abstract

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