Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = malonate dianion, DMF = N,N-dimethylformamide, pyz = pyrazine)

Tian Fu Liu, Hao Ling Sun, Song Gao*, Shi Wei Zhang, Tai Chu Lau

*Corresponding author for this work

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Abstract

Two three-dimensional (3D) malonate bridged networks, [Cu(mal)(DMF)]n (1) and {[Cu(mal)(0.5pyz)]·H2O}n (2), have been synthesized in H2O-DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (Tc), and displays a metamagnetic behavior below 3.2 K (TN).

Original languageEnglish
Pages (from-to)4792-4794
Number of pages3
JournalInorganic Chemistry
Volume42
Issue number16
DOIs
Publication statusPublished - 11 Aug 2003
Externally publishedYes

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Liu, T. F., Sun, H. L., Gao, S., Zhang, S. W., & Lau, T. C. (2003). Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = malonate dianion, DMF = N,N-dimethylformamide, pyz = pyrazine). Inorganic Chemistry, 42(16), 4792-4794. https://doi.org/10.1021/ic034346x