Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization

Xing Dong Xu; Chang Jiang Yao; Li Jun Chen; Guang Qiang Yin; Yu Wu Zhong; Hai Bo Yang

doi:10.1002/chem.201504480

Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization

Xing Dong Xu, Chang Jiang Yao, Li Jun Chen, Guang Qiang Yin, Yu Wu Zhong^*, Hai Bo Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The construction of well-controlled porous materials is very challenging. Herein, we report the successful preparation of structurally defined porous membranes based on hexakistriphenylamine metallacycles through electropolymerization. The newly designed porous materials were characterized by the typical cyclic voltammograms, XPS, SEM, and TEM investigations. Further investigations revealed that the metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior. Molecular sieving: The successful preparation of structurally defined porous membranes based on a hexakistriphenylamine metallacycle through electropolymerization is reported. Further investigations revealed that metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior.

Original language	English
Pages (from-to)	5211-5218
Number of pages	8
Journal	Chemistry - A European Journal
Volume	22
Issue number	15
DOIs	https://doi.org/10.1002/chem.201504480
Publication status	Published - 4 Apr 2016
Externally published	Yes

Keywords

electropolymerization
metallacycles
molecular sieving
porous materials
supramolecular chemistry

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10.1002/chem.201504480

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title = "Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization",

abstract = "The construction of well-controlled porous materials is very challenging. Herein, we report the successful preparation of structurally defined porous membranes based on hexakistriphenylamine metallacycles through electropolymerization. The newly designed porous materials were characterized by the typical cyclic voltammograms, XPS, SEM, and TEM investigations. Further investigations revealed that the metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior. Molecular sieving: The successful preparation of structurally defined porous membranes based on a hexakistriphenylamine metallacycle through electropolymerization is reported. Further investigations revealed that metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior.",

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AU - Xu, Xing Dong

AU - Yao, Chang Jiang

AU - Chen, Li Jun

AU - Yin, Guang Qiang

AU - Zhong, Yu Wu

AU - Yang, Hai Bo

PY - 2016/4/4

Y1 - 2016/4/4

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AB - The construction of well-controlled porous materials is very challenging. Herein, we report the successful preparation of structurally defined porous membranes based on hexakistriphenylamine metallacycles through electropolymerization. The newly designed porous materials were characterized by the typical cyclic voltammograms, XPS, SEM, and TEM investigations. Further investigations revealed that the metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior. Molecular sieving: The successful preparation of structurally defined porous membranes based on a hexakistriphenylamine metallacycle through electropolymerization is reported. Further investigations revealed that metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior.

KW - electropolymerization

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KW - porous materials

KW - supramolecular chemistry

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Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization

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Keywords

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