Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

Jiawei Wan; Di Liu; Hai Xiao; Hongpan Rong; Sheng Guan; Feng Xie; Dingsheng Wang; Yadong Li

doi:10.1039/d0cc00700e

Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

Jiawei Wan, Di Liu, Hai Xiao, Hongpan Rong, Sheng Guan, Feng Xie, Dingsheng Wang, Yadong Li

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The facet effect has been well demonstrated for nanocrystal catalysis, however it is rarely revealed in metal organic frameworks (MOFs). Herein, we present a facile way to construct 2D zeolitic imidazolate framework-67 (ZIF-67) with dominant exposure of the (002) facets. We discovered that the ZIF-67 (002) facet exhibited the highest catalytic activity for oxygen evolution reaction (OER) among the (002), (011), and (111) facets. Moreover, this facet engineering is also available for ZIF-8 nanocrystals.

Original language	English
Pages (from-to)	4316-4319
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	31
DOIs	https://doi.org/10.1039/d0cc00700e
Publication status	Published - 21 Apr 2020

Access to Document

10.1039/d0cc00700e

Cite this

@article{e9bfc505b8d146eeae0da7824dcb0aa9,

title = "Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation",

abstract = "The facet effect has been well demonstrated for nanocrystal catalysis, however it is rarely revealed in metal organic frameworks (MOFs). Herein, we present a facile way to construct 2D zeolitic imidazolate framework-67 (ZIF-67) with dominant exposure of the (002) facets. We discovered that the ZIF-67 (002) facet exhibited the highest catalytic activity for oxygen evolution reaction (OER) among the (002), (011), and (111) facets. Moreover, this facet engineering is also available for ZIF-8 nanocrystals.",

author = "Jiawei Wan and Di Liu and Hai Xiao and Hongpan Rong and Sheng Guan and Feng Xie and Dingsheng Wang and Yadong Li",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

month = apr,

day = "21",

doi = "10.1039/d0cc00700e",

language = "English",

volume = "56",

pages = "4316--4319",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

AU - Wan, Jiawei

AU - Liu, Di

AU - Xiao, Hai

AU - Rong, Hongpan

AU - Guan, Sheng

AU - Xie, Feng

AU - Wang, Dingsheng

AU - Li, Yadong

PY - 2020/4/21

Y1 - 2020/4/21

N2 - The facet effect has been well demonstrated for nanocrystal catalysis, however it is rarely revealed in metal organic frameworks (MOFs). Herein, we present a facile way to construct 2D zeolitic imidazolate framework-67 (ZIF-67) with dominant exposure of the (002) facets. We discovered that the ZIF-67 (002) facet exhibited the highest catalytic activity for oxygen evolution reaction (OER) among the (002), (011), and (111) facets. Moreover, this facet engineering is also available for ZIF-8 nanocrystals.

AB - The facet effect has been well demonstrated for nanocrystal catalysis, however it is rarely revealed in metal organic frameworks (MOFs). Herein, we present a facile way to construct 2D zeolitic imidazolate framework-67 (ZIF-67) with dominant exposure of the (002) facets. We discovered that the ZIF-67 (002) facet exhibited the highest catalytic activity for oxygen evolution reaction (OER) among the (002), (011), and (111) facets. Moreover, this facet engineering is also available for ZIF-8 nanocrystals.

UR - http://www.scopus.com/inward/record.url?scp=85083589804&partnerID=8YFLogxK

U2 - 10.1039/d0cc00700e

DO - 10.1039/d0cc00700e

M3 - Article

C2 - 32187248

AN - SCOPUS:85083589804

SN - 1359-7345

VL - 56

SP - 4316

EP - 4319

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Facet engineering in metal organic frameworks to improve their electrochemical activity for water oxidation

Abstract

Access to Document

Other files and links

Fingerprint

Cite this