Fabrication of eco-friendly and multifunctional sodium-containing polyhedral oligomeric silsesquioxane and its flame retardancy on epoxy resin

Xinming Ye; Jingjing Li; Wenchao Zhang; Rongjie Yang; Jiarong Li

doi:10.1016/j.compositesb.2020.107961

Fabrication of eco-friendly and multifunctional sodium-containing polyhedral oligomeric silsesquioxane and its flame retardancy on epoxy resin

Xinming Ye, Jingjing Li, Wenchao Zhang, Rongjie Yang^*, Jiarong Li

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Considering the reduction of fire hazards associated with the application of epoxy resin (EP) composites. Herein, a novel sodium-containing polyhedral oligomeric phenyl silsesquioxane (Na-Ph-POSS) has been synthesized through hydrolysis condensation. FTIR, NMR and MALDI-TOF MS results reveal that Na-Ph-POSS is a hepta-phenyl POSS consisting of Si–O–Na and Si–OH groups. Compared to pure EP, according to the combustion results, the peak of heat release rate (p-HRR), the maximum smoke density (Ds, max) and the peak of CO production rate (p-COP) of EP/5 wt% Na-Ph-POSS significantly decrease by 45.9, 45.1 and 46.9%, respectively. Additionally, EP composites endowed with Na-Ph-POSS have low dielectric constant and dielectric loss. Therefore, eco-friendly multifunctional Na-Ph-POSS provides a promising prospect for mitigating the fire hazards of EP composites.

Original language	English
Article number	107961
Journal	Composites Part B: Engineering
Volume	191
DOIs	https://doi.org/10.1016/j.compositesb.2020.107961
Publication status	Published - 15 Jun 2020

Keywords

Dielectric constant
Epoxy resin
Flame retardancy
Na-Ph-POSS
Smoke suppression

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title = "Fabrication of eco-friendly and multifunctional sodium-containing polyhedral oligomeric silsesquioxane and its flame retardancy on epoxy resin",

abstract = "Considering the reduction of fire hazards associated with the application of epoxy resin (EP) composites. Herein, a novel sodium-containing polyhedral oligomeric phenyl silsesquioxane (Na-Ph-POSS) has been synthesized through hydrolysis condensation. FTIR, NMR and MALDI-TOF MS results reveal that Na-Ph-POSS is a hepta-phenyl POSS consisting of Si–O–Na and Si–OH groups. Compared to pure EP, according to the combustion results, the peak of heat release rate (p-HRR), the maximum smoke density (Ds, max) and the peak of CO production rate (p-COP) of EP/5 wt% Na-Ph-POSS significantly decrease by 45.9, 45.1 and 46.9%, respectively. Additionally, EP composites endowed with Na-Ph-POSS have low dielectric constant and dielectric loss. Therefore, eco-friendly multifunctional Na-Ph-POSS provides a promising prospect for mitigating the fire hazards of EP composites.",

keywords = "Dielectric constant, Epoxy resin, Flame retardancy, Na-Ph-POSS, Smoke suppression",

author = "Xinming Ye and Jingjing Li and Wenchao Zhang and Rongjie Yang and Jiarong Li",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd",

year = "2020",

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doi = "10.1016/j.compositesb.2020.107961",

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AU - Ye, Xinming

AU - Li, Jingjing

AU - Zhang, Wenchao

AU - Yang, Rongjie

AU - Li, Jiarong

PY - 2020/6/15

Y1 - 2020/6/15

N2 - Considering the reduction of fire hazards associated with the application of epoxy resin (EP) composites. Herein, a novel sodium-containing polyhedral oligomeric phenyl silsesquioxane (Na-Ph-POSS) has been synthesized through hydrolysis condensation. FTIR, NMR and MALDI-TOF MS results reveal that Na-Ph-POSS is a hepta-phenyl POSS consisting of Si–O–Na and Si–OH groups. Compared to pure EP, according to the combustion results, the peak of heat release rate (p-HRR), the maximum smoke density (Ds, max) and the peak of CO production rate (p-COP) of EP/5 wt% Na-Ph-POSS significantly decrease by 45.9, 45.1 and 46.9%, respectively. Additionally, EP composites endowed with Na-Ph-POSS have low dielectric constant and dielectric loss. Therefore, eco-friendly multifunctional Na-Ph-POSS provides a promising prospect for mitigating the fire hazards of EP composites.

AB - Considering the reduction of fire hazards associated with the application of epoxy resin (EP) composites. Herein, a novel sodium-containing polyhedral oligomeric phenyl silsesquioxane (Na-Ph-POSS) has been synthesized through hydrolysis condensation. FTIR, NMR and MALDI-TOF MS results reveal that Na-Ph-POSS is a hepta-phenyl POSS consisting of Si–O–Na and Si–OH groups. Compared to pure EP, according to the combustion results, the peak of heat release rate (p-HRR), the maximum smoke density (Ds, max) and the peak of CO production rate (p-COP) of EP/5 wt% Na-Ph-POSS significantly decrease by 45.9, 45.1 and 46.9%, respectively. Additionally, EP composites endowed with Na-Ph-POSS have low dielectric constant and dielectric loss. Therefore, eco-friendly multifunctional Na-Ph-POSS provides a promising prospect for mitigating the fire hazards of EP composites.

KW - Dielectric constant

KW - Epoxy resin

KW - Flame retardancy

KW - Na-Ph-POSS

KW - Smoke suppression

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SN - 1359-8368

VL - 191

JO - Composites Part B: Engineering

JF - Composites Part B: Engineering

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ER -

Fabrication of eco-friendly and multifunctional sodium-containing polyhedral oligomeric silsesquioxane and its flame retardancy on epoxy resin

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Keywords

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