Exploring reversible oxidation of oxygen in a manganese oxide

Ke Du; Jinyou Zhu; Guorong Hu; Hongcai Gao; Yutao Li; John B. Goodenough

doi:10.1039/c6ee01367h

Exploring reversible oxidation of oxygen in a manganese oxide

Ke Du, Jinyou Zhu, Guorong Hu, Hongcai Gao, Yutao Li, John B. Goodenough^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

192 Citations (Scopus)

Abstract

Nominal Na_0.6(Li_0.2Mn_0.8)O₂ with the layered P3 structure (s.g. R3m) showed XPS evidence of holes in the O-2p bands on removal of Na⁺ ions. A large voltage plateau at 4.1 V versus Na⁺/Na faded significantly over 50 cycles although the capacity in the range 20 ≤ V < 4.5 V remained unchanged. Oxidation of the O-2p bands is not reversible.

Original language	English
Pages (from-to)	2575-2577
Number of pages	3
Journal	Energy and Environmental Science
Volume	9
Issue number	8
DOIs	https://doi.org/10.1039/c6ee01367h
Publication status	Published - Aug 2016
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c6ee01367h

Cite this

@article{f7228df5dd6e41f1888abfd51ad2bbea,

title = "Exploring reversible oxidation of oxygen in a manganese oxide",

abstract = "Nominal Na0.6(Li0.2Mn0.8)O2 with the layered P3 structure (s.g. R3m) showed XPS evidence of holes in the O-2p bands on removal of Na+ ions. A large voltage plateau at 4.1 V versus Na+/Na faded significantly over 50 cycles although the capacity in the range 20 ≤ V < 4.5 V remained unchanged. Oxidation of the O-2p bands is not reversible.",

author = "Ke Du and Jinyou Zhu and Guorong Hu and Hongcai Gao and Yutao Li and Goodenough, {John B.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

month = aug,

doi = "10.1039/c6ee01367h",

language = "English",

volume = "9",

pages = "2575--2577",

journal = "Energy and Environmental Science",

issn = "1754-5692",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Exploring reversible oxidation of oxygen in a manganese oxide

AU - Du, Ke

AU - Zhu, Jinyou

AU - Hu, Guorong

AU - Gao, Hongcai

AU - Li, Yutao

AU - Goodenough, John B.

PY - 2016/8

Y1 - 2016/8

N2 - Nominal Na0.6(Li0.2Mn0.8)O2 with the layered P3 structure (s.g. R3m) showed XPS evidence of holes in the O-2p bands on removal of Na+ ions. A large voltage plateau at 4.1 V versus Na+/Na faded significantly over 50 cycles although the capacity in the range 20 ≤ V < 4.5 V remained unchanged. Oxidation of the O-2p bands is not reversible.

AB - Nominal Na0.6(Li0.2Mn0.8)O2 with the layered P3 structure (s.g. R3m) showed XPS evidence of holes in the O-2p bands on removal of Na+ ions. A large voltage plateau at 4.1 V versus Na+/Na faded significantly over 50 cycles although the capacity in the range 20 ≤ V < 4.5 V remained unchanged. Oxidation of the O-2p bands is not reversible.

UR - http://www.scopus.com/inward/record.url?scp=84982965063&partnerID=8YFLogxK

U2 - 10.1039/c6ee01367h

DO - 10.1039/c6ee01367h

M3 - Article

AN - SCOPUS:84982965063

SN - 1754-5692

VL - 9

SP - 2575

EP - 2577

JO - Energy and Environmental Science

JF - Energy and Environmental Science

IS - 8

ER -

Exploring reversible oxidation of oxygen in a manganese oxide

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this