Engineering a metal-organic framework derived Mn-N4-C: X Sy atomic interface for highly efficient oxygen reduction reaction

Huishan Shang; Zhuoli Jiang; Danni Zhou; Jiajing Pei; Yu Wang; Juncai Dong; Xusheng Zheng; Jiatao Zhang; Wenxing Chen

doi:10.1039/d0sc02343d

Engineering a metal-organic framework derived Mn-N₄-C_{: X}S_yatomic interface for highly efficient oxygen reduction reaction

Huishan Shang, Zhuoli Jiang, Danni Zhou, Jiajing Pei, Yu Wang, Juncai Dong, Xusheng Zheng, Jiatao Zhang, Wenxing Chen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

122 Citations (Scopus)

Abstract

Atomic interface engineering is an effective pathway to regulate the performance of single metal atom catalysts for electrochemical reactions in energy applications. Herein, we construct a sulfur modified Mn-N-C single atom catalyst through a metal-organic framework derived atomic interface strategy, which exhibits outstanding ORR activity with a half-wave potential of 0.916 V vs. RHE in alkaline media. Moreover, operando X-ray absorption spectroscopy analysis indicates that the isolated bond-length extending the low-valence Mn-N4-CxSy moiety serves as an active site during the ORR process. These findings suggest a promising method for the advancement of single atom catalysis.

Original language	English
Pages (from-to)	5994-5999
Number of pages	6
Journal	Chemical Science
Volume	11
Issue number	23
DOIs	https://doi.org/10.1039/d0sc02343d
Publication status	Published - 21 Jun 2020

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title = "Engineering a metal-organic framework derived Mn-N4-C: X Sy atomic interface for highly efficient oxygen reduction reaction",

abstract = "Atomic interface engineering is an effective pathway to regulate the performance of single metal atom catalysts for electrochemical reactions in energy applications. Herein, we construct a sulfur modified Mn-N-C single atom catalyst through a metal-organic framework derived atomic interface strategy, which exhibits outstanding ORR activity with a half-wave potential of 0.916 V vs. RHE in alkaline media. Moreover, operando X-ray absorption spectroscopy analysis indicates that the isolated bond-length extending the low-valence Mn-N4-CxSy moiety serves as an active site during the ORR process. These findings suggest a promising method for the advancement of single atom catalysis.",

author = "Huishan Shang and Zhuoli Jiang and Danni Zhou and Jiajing Pei and Yu Wang and Juncai Dong and Xusheng Zheng and Jiatao Zhang and Wenxing Chen",

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T1 - Engineering a metal-organic framework derived Mn-N4-C: X Sy atomic interface for highly efficient oxygen reduction reaction

AU - Shang, Huishan

AU - Jiang, Zhuoli

AU - Zhou, Danni

AU - Pei, Jiajing

AU - Wang, Yu

AU - Dong, Juncai

AU - Zheng, Xusheng

AU - Zhang, Jiatao

AU - Chen, Wenxing

PY - 2020/6/21

Y1 - 2020/6/21

N2 - Atomic interface engineering is an effective pathway to regulate the performance of single metal atom catalysts for electrochemical reactions in energy applications. Herein, we construct a sulfur modified Mn-N-C single atom catalyst through a metal-organic framework derived atomic interface strategy, which exhibits outstanding ORR activity with a half-wave potential of 0.916 V vs. RHE in alkaline media. Moreover, operando X-ray absorption spectroscopy analysis indicates that the isolated bond-length extending the low-valence Mn-N4-CxSy moiety serves as an active site during the ORR process. These findings suggest a promising method for the advancement of single atom catalysis.

AB - Atomic interface engineering is an effective pathway to regulate the performance of single metal atom catalysts for electrochemical reactions in energy applications. Herein, we construct a sulfur modified Mn-N-C single atom catalyst through a metal-organic framework derived atomic interface strategy, which exhibits outstanding ORR activity with a half-wave potential of 0.916 V vs. RHE in alkaline media. Moreover, operando X-ray absorption spectroscopy analysis indicates that the isolated bond-length extending the low-valence Mn-N4-CxSy moiety serves as an active site during the ORR process. These findings suggest a promising method for the advancement of single atom catalysis.

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VL - 11

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EP - 5999

JO - Chemical Science

JF - Chemical Science

IS - 23

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Engineering a metal-organic framework derived Mn-N₄-C_{: X}S_yatomic interface for highly efficient oxygen reduction reaction

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